Klappentext

Introduction to the Mechanochemistry of Solids offers a thorough exploration of mechanochemistry, a field rapidly reshaping modern chemistry by enabling solvent-free, efficient synthesis of materials. The book serves as a vital resource for those new to solid-state reactivity, presenting foundational theories and practical insights that illuminate how mechanical forces can drive chemical change. Readers are introduced to the complexities of mechanochemical processes, the nuances of device selection, and the impact of sample preparation, providing a solid framework for understanding how physical forces influence chemical transformations in solids.

In addition, the book discusses the growing diversity of scientists contributing to mechanochemistry and outlines the transformative potential of this technology for sustainable and green chemistry. It is especially recommended for advanced undergraduate and graduate students as well as researchers in chemistry, materials science, and related fields.

Inhalt

SECTION I: THE SOLID STATE AS A UNIQUE CHEMICAL PLAYGROUND

1. Basic features of solid-state structure
2. Thermodynamic landscape of the solid state
3. Defects: changing solid state stability and reactivity

SECTION II: NATURE OF MECHANOCHEMICAL REACTIONS IN SOLIDS
4. Avenues for reactivity in solids
5. Thermo-mechanical reactivity of solids
6. Reactivity of solids under dynamic mechanical strain
7. Are mechano-chemical reactions always ‘mechano-chemical’?
8. Energetic aspects of solid state mechanochemical reactions
9. Elementary kinetics of mechanochemical reactions

SECTION III: EXPERIMENTAL AND THEORETICAL METHODS TO STUDY SOLID STATE MECHANOCHEMISTRY
10. Solution analytical methods in solid state mechanochemistry
11. Main techniques for solid state characterisation to study mechanochemical reactions (diffraction including Rietveld and microstructure, thermal analysis, etc)
12. Progress in methods to study mechanochemical reactions in situ
13. Theoretical methods to study mechanochemical reactions in solids
14. Designing a mechanochemical reaction from first principles

SECTION IV: APPLICATIONS OF MECHANOCHEMISTRY
15. Mechanochemistry for organic synthesis
16. Mechanochemistry for inorganic synthesis
17. Mechanochemistry for the design of molecular materials (cocrystal, MOF, COF, etc)
18. Mechanochemistry in pharmacy
19. Mechanochemistry of natural materials
20. Mechanochemistry for sustainable chemistry / manufacture
21. Mechanochemistry for industrial applications: scale-up