The Chemical Transformations of C1 Compounds

This three-volume reference book provides an in-depth overview of recent developments and significant progress in the field of C1 chemistry, covering all major C1 compounds e.g. methane, methanol, formic acid, carbon monoxide and carbon dioxide.

Autorentext

*Xiao-Feng Wu, PhD, has published over 400 publications in international journals and is the editor or author of 10 books. He received his doctorate from the Leibniz Institute for Catalysis in Germany.*

*Buxing Han, PhD, is Professor and Academician at the Institute of Chemistry, Chinese Academy of Sciences. He has published more than 300 papers and authored over 20 patents. He received his doctorate from the Chinese Academy of Sciences in 1988. * Kuiling Ding, PhD,* is Executive Vice President at Shanghai Jiaotong University. He received his doctorate in 1990 from Nanjing University and is a member of the Chinese Academy of Sciences. **Zhongmin Liu, PhD, is Director of the Dalian Institute of Chemical Physics and the Qingdao Institute of Bioenergy and Bioprocess Technology. He received his doctorate in Physical Chemistry from the Dalian Institute of Chemical Physics in 1990.*

Klappentext
A comprehensive exploration of one-carbon molecule transformations

The chemistry of one-carbon molecules has recently gained significant prominence as the world transitions away from a petroleum-based economy to a more sustainable one. In The Chemical Transformations of C1 Compounds, an accomplished team of chemists delivers an in-depth overview of recent developments in the field of single-carbon chemistry. The three-volume book covers all major C1 sources, including carbon monoxide, carbon dioxide, methane, methanol, formic acid, formaldehyde, carbenes, C1 halides, and organometallics. The editors have included resources discussing the main reactions and transformations into feedstock chemicals of each of the major C1 compounds reviewed in dedicated chapters. Readers will discover cutting-edge material on organic transformations with MeNO2, DMF, DCM, methyl organometallic reagents, CCl4, CHCl3, and CHBr3, as well as recent achievements in cyanation reactions via cross-coupling. The book also offers:

• Thorough introductions to chemical transformations of CH4, methods of CH4 activation, chemical transformations of CH3OH and synthesis alkenes from CH3OH
• Comprehensive explorations of the carbonylation of MeOH, CH2O in organic synthesis, organic transformations of HCO2H, and hydrogen generation from HCO2H
• Practical discussions of the carbonylation of unsaturated bonds with heterogeneous and homogeneous catalysts, as well as the carbonylation of C(sp2)-X bonds and C(sp3)-X bonds
• In-depth examinations of carbonylative C-H bond activation and radical carbonylation Perfect for organic and catalytic chemists, The Chemical Transformations of C1 Compounds is also an ideal resource for industrial chemists, chemical engineers, and practitioners at energy supply companies.

Zusammenfassung
The Chemical Transformations of C1 Compounds A comprehensive exploration of one-carbon molecule transformations The chemistry of one-carbon molecules has recently gained significant prominence as the world transitions away from a petroleum-based economy to a more sustainable one. In The Chemical Transformations of C1 Compounds, an accomplished team of chemists delivers an in-depth overview of recent developments in the field of single-carbon chemistry. The three-volume book covers all major C1 sources, including carbon monoxide, carbon dioxide, methane, methanol, formic acid, formaldehyde, carbenes, C1 halides, and organometallics. The editors have included resources discussing the main reactions and transformations into feedstock chemicals of each of the major C1 compounds reviewed in dedicated chapters. Readers will discover cutting-edge material on organic transformations with MeNO2, DMF, DCM, methyl organometallic reagents, CCl4, CHCl3, and CHBr3, as well as recent achievements in cyanation reactions via cross-coupling. The book also offers:

• Thorough introductions to chemical transformations of CH4, methods of CH4 activation, chemical transformations of CH3OH and synthesis alkenes from CH3OH
• Comprehensive explorations of the carbonylation of MeOH, CH2O in organic synthesis, organic transformations of HCO2H, and hydrogen generation from HCO2H
• Practical discussions of the carbonylation of unsaturated bonds with heterogeneous and homogeneous catalysts, as well as the carbonylation of C(sp2)-X bonds and C(sp3)-X bonds
• In-depth examinations of carbonylative C-H bond activation and radical carbonylation Perfect for organic and catalytic chemists, The Chemical Transformations of C1 Compounds is also an ideal resource for industrial chemists, chemical engineers, and practitioners at energy supply companies.

Inhalt
Direct Conversions of Methane via Homogeneous Processes

Chemical transformations of methanol

Synthesis alkenes from CH3OH

Formaldehyde as C1 Synthon in Organic Synthesis

Organic transformations of HCO2H

The Multifunctional Materials for Heterogenous Carboxylation: from Fundamental Understanding into Industrial Applications

Recent hydrocarbonylation of unsaturated hydrocarbons with homogeneous catalyst

Carbonylation of C(sp2)-X bonds

Carbonylation of C(sp3)-X bonds utilizing CO

Carbonylative C-H bond activation

Recent Advances in Radical Carbonylation

Asymmetric carbonylation reactions

Carbonylative Synthesis of DPC (Diphenyl Carbonate)

Oxidative carbonyltaion of amines

Carbonylation of nitroarenes and related compounds

Zeolite-Catalyzed Carbonylation of Dimethyl Ether

Complex Natural Product Total Syntheses Facilitated by Palladium-Catalyzed Carbonylative Cyclizations

Metal-Catalyzed Alternating Polymerization Reactions with Carbon Monoxide

CO hydrogenation

Carboxylation with Carbon Dioxide as a C1 Source via Carbon-Carbon Bond Forming Reactions

Cyclization reactions with CO2

Reduction of CO2 to formic acid

Reduction of CO2 to CO and Their Applications

Hydrogenation of CO2 to Chemicals with Green Hydrogen

Methylation reactions with CO2

Using CO2 as -CH2- and -CH- sources

Catalytic asymmetric transformation of CO2

Polymerization reactions with CO2

Transition Metal Catalyzed C-CN Cross-Coupling

Recent advancement in transition-metal-catalyzed hydrocyanation of nonpolar unsaturated compounds

Organic transformations with MeNO2

Applications of DMF as a Reagent in Organic Synthesis

Advances in the synthesis of methylated products through direct approaches: a guide for selecting methylation reagents

Organic transformations with DCM, CCl4, CHCl3, and CHBr3 and other related reactions

Trifluoromethylation with CF3I and other related reagents

The applications of dimethyl sulfoxide as a one-carbon source in organic synthesis