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Edited by foremost leaders in chemical research together with a number of distinguished international authors, this fourth volume summarizes the most important and promising recent developments in synthesis, polymer chemistry and supramolecular chemisty. Interdisciplinary and application-oriented, this ready reference focuses on innovative methods, covering new developments in catalysis, synthesis, polymers and more.
Autorentext
Hisashi Yamamoto is Professor at the University of Chicago. He received his Ph.D. from Harvard under the mentorship of Professor E. J. Corey. His first academic position was as Assistant Professor and lecturer at Kyoto University, and in 1977 he was appointed Associate Professor of Chemistry at the University of Hawaii. In 1980 he moved to Nagoya University where he became Professor in 1983. In 2002, he moved to United States as Professor at the University of Chicago. He has been honored to receive the Prelog Medal in 1993, the Chemical Society of Japan Award in 1995, the National Prize of Purple Medal (Japan) in 2002, Yamada Prize in 2004, and Tetrahedron Prize in 2006 and the ACS Award for Creative Work in Synthetic Organic Chemistry to name a few. He authored more than 500 papers, 130 reviews and books (h-index ~90).
Takashi Kato is a Professor at the Department of Chemistry and Biotechnology at the University of Tokyo since 2000. After his postdoctoral research at Cornell University, Department of Chemistry with Professor Jean M. J. Frechet, he joined the University of Tokyo. He is the recipient of The Chemical Society of Japan Award for Young Chemists (1993), The Wiley Polymer Science Award (Chemistry), the 17th IBM Japan Science Award (Chemistry), the 1st JSPS (Japan Society for the Promotion of Science) Prize and the Award of Japanese Liquid Crystal Society (2008). He is the editor in chief of the "Polymer Journal", and member of the editorial board of "New Journal of Chemistry".
Inhalt
1 Polymerization-Induced Self-assembly of Block Copolymer Nano-objects via Green RAFT Polymerization **1
**Shinji Sugihara
1.1 Introduction 1
1.2 Block Copolymer Solution 1
1.3 Synthesis of Block Copolymers via RAFT Polymerization 4
1.4 Polymerization-Induced Self-assembly 6
1.4.1 PISA Using RAFT Process: Emulsion and Aqueous Dispersion Polymerization 6
1.4.2 Reagents for RAFT Aqueous Dispersion Polymerization 9
1.4.2.1 RAFT Agents 9
1.4.2.2 Steric Stabilizer (Macro-CTA, Shell) 9
1.4.2.3 Monomers (Core) 9
1.4.3 Representative RAFT Aqueous Dispersion Polymerization 11
1.5 Promising Polymerization Technology 17
References 21
2 Chemical Functionalization of Graphitic Nanocarbons **31
**Yuta Nishina
2.1 Purpose of Functionalization 31
2.2 Edge Functionalization 34
2.3 Basal Plane Functionalization 37
2.3.1 Hydrogenation and Halogenation 37
2.3.2 Radical Addition 37
2.3.3 Cycloaddition 40
2.4 Miscellaneous 42
2.4.1 Oxidation 42
2.4.2 Covalent Bond Formation via Halogenation 42
2.4.3 Rearrangement 42
2.5 Non-covalent Functionalization 44
2.5.1 Functionalization with Interactions 45
2.5.2 Functionalization with van der Waals, Ionic Interactions, and Hydrogen Bonding 45
2.5.3 Functionalization with Polymers 46
2.6 Future Perspective of Graphitic Nanocarbon Functionalization 48
References 48
3 Synthetic Methods Using Interactions Between Sustainable Iron Reagents and Functionalized CarbonCarbon Multiple Bonds **51
**Takeshi Hata
3.1 Cross-coupling Reactions 52
3.1.1 C(sp2)X/C(sp3)Metal 52
3.1.2 C(sp2)X/C(sp2)Metal 54
3.1.3 C(sp2)X/C(sp)Metal 55
3.1.4 C(sp)X/C(sp2)Metal 55
3.1.5 C(sp3)X/C(sp2)Metal 55
3.1.6 MizorokiHeck Reaction 56
3.2 Substitution Reactions 56
3.3 Carbometallation 58
3.4 Conjugate Addition 59
3.5 Cycloaddition 67
3.5.1 [2+2] Cycloadditions 67
3.5.2 [3+2] Cycloadditions 68
3.5.3 [4+1] Cycloadditions 68
3.5.4 [4+2] Cycloadditions 68
3.5.5 1,3-Dipolar Cycloadditions 70
3.6 Others 71
3.6.1 CH Bond Activation 71
3.6.2 Nazarov Cyclization 72
3.6.3 FriedelCrafts Reaction 72
3.7 Conclusion 73
References 73
4 Molecular Technology for Switch and Amplification of Chirality in Asymmetric Catalysis Using a Helically Dynamic Macromolecular Scaffold as a Source of Chirality **77
**Michinori Suginome
4.1 Introduction 77
4.2 Molecular Design and Synthesis of PQX-Based Chiral Catalysts 79
4.3 Dynamic, Bidirectional Induction of Helical Chirality to PQX 81
4.4 PQX as Chirality-Switchable Chiral Catalysts in Catalytic Asymmetric Synthesis 82
4.4.1 Palladium-Catalyzed Asymmetric Reactions Using PQXphos Bearing Monophosphine Pendants on PQX 82
4.4.2 Copper-Catalyzed Asymmetric Reactions Using PQXbpy Bearing 2,2'-Bipyridin-6-yl Pendants on PQX 87
4.4.3 Organocatalytic Asymmetric Reactions Using PQXap Bearing 4-Aminopyridin-3-yl Pendants on PQX 88
4.5 Chirality Amplification in Asymmetric Catalysis 90
4.6 Closing Remarks 92
References 92
5 Cooperative Double Activation Metal/Metal and Metal/Organic Catalysis Enabling Challenging Organic Reactions **95
**Yoshiaki Nakao
5.1 Introduction 95
5.2 CH Functionalization by Cooperative Double Activation Catalysis 96
5.3 CC Functionalization by Cooperative Double Activation Catalysis 106 5....