Hypervalent Iodine-Induced Oxidative Couplings (New Metal-Free Coupling Advances and Their Applications in Natural Product Syntheses) -- Toshifumi Dohi and Yasuyuki Kita Phenol Dearomatization with Hypervalent Iodine Reagents -- Stéphane Quideau, Laurent Pouységu, Philippe A. Peixoto,and Denis Deffieux Oxidative Heterocycle Formation Using Hypervalent Iodine(III) Reagents -- Sandip Murarka and Andrey P. Antonchick Aminations with Hypervalent Iodine -- Kilian Muñiz Arylation with Diaryliodonium Salts -- Berit Olofsson Iodanes as Trifluoromethylation Reagents -- Natalja Früh, Julie Charpentier, and Antonio Togni Alkynylation with Hypervalent Iodine Reagents -- Jerome Waser Rearrangements Induced by Hypervalent Iodine -- Gaëtan Maertens, Sylvain Canesi Asymmetric Synthesis with Hypervalent Iodine Reagents -- Ravi Kumar, Thomas Wirth Organoiodine(III) Reagents as Active Participants and Ligands in Transition Metal-Catalyzed Reactions: Iodosylarenes and (Imino)iodoarenes -- John D. Protasiewicz Halogen Bonding in Hypervalent Iodine Compounds -- Luca Catalano, Gabriella Cavallo, Pierangelo Metrangolo , Giuseppe Resnati , Giancarlo Terraneo

Klappentext

The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students.

Inhalt

Oxidative Coupling Reactions mediated by Hypervalent Iodine Reagents.- Phenol Dearomatization with Hypervalent Iodine Reagents.- Oxidative Heterocycle formation using Hypervalent Iodine Reagents.- Aminations with Hypervalent Iodine.- Arylation with Diaryliodium Salts.- Trifluoromethylation using Cyclic Iodine Derivatives.- Alkynylation with Iodine Reagents.- Rearrangements induced by Iodine Reagents.- Stereoselective Reactions with Hypervalent Iodine Reagents.- Hypervalent Iodine Reagents in Transition Metal Catalysis.- Halogen Bonding in Hypervalent Iodine Reagents.