This second edition presents an enriched and expanded exploration of the fundamental principles of thermodynamics tailored for graduate-level studies. Drawing on over three decades of academic teaching experience, the author has refined the content, making it more accessible and comprehensive. Chapter 1 has been restructured for clarity, delineating "Legendre Transformation" and "Thermodynamic Potentials" into separate sections, while the treatment of "Chemical Potentials" has been significantly augmented, encompassing two-component ideal gas mixtures and a re-derivation of chemical potentials for dilute solutions. Additionally, the section on thermodynamic stability now boasts enhanced explanations and illustrative figures. Chapter 2 introduces a groundbreaking section, "Electrolyte Solution in Electric Field as a Non-Uniform System," providing fresh insights into unexplored realms. Chapter 3, now enriched with several new sections, delves into topics such as "Contact Angles on Heterogeneous Surfaces and Rough Surfaces," "Elastic Liquid-Fluid Interface," "Curvature Effect on Surface Tension," "Solute Effect on Equilibrium Pressure," and "Heterogeneous Bubble Nucleation in a Dilute Solution." Chapter 4 features new elucidations and discussions aimed at bolstering comprehension, while the entirely new Chapter 5 offers solutions to selected homework and exam questions, adding a practical dimension to the theoretical framework. This edition, encompassing approximately 50% new content, expands the book by 131 pages, rendering it an even more invaluable resource for professors instructing advanced thermodynamics and graduate students delving into this intricate subject matter.

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Dongqing Li obtained his Ph.D. degree at the University of Toronto in 1991. In 1993, Dr. Li joined the faculty of the Department of Mechanical Engineering, University of Alberta, where he obtained tenure in 1997 and was promoted to the rank of full professor in 1999. He later joined the Department of Mechanical and Industrial Engineering, University of Toronto, in 2000 as a tenured full professor. From October 2005 to August 2008, Dr. Li was the H. Fort Flowers Chair Professor of Mechanical Engineering at Vanderbilt University, USA. Since September 2008, Dr. Li has joined the University of Waterloo as a tenured full professor, and he was the Canada Research Chair in Microfluidics and Nanofluidics from 2008 to 2013.