Differentiation of Enantiomers I

The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science.The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience.Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Inhalt

Molecular Chirality: Language, History, and Significance.- Chiral Supramolecular Selectors for Enantiomer Differentiation in Liquid Chromatography.- Anisotropy Spectra for Enantiomeric Differentiation of Biomolecular Building Blocks.- Chiroptical Detectors for the Study of Unusual Phenomena in Chiral Chromatography.- Salient Features of Enantioselective Gas Chromatography: The Enantiomeric Differentiation of Chiral Inhalation Anesthetics as a Representative Methodological Case in Point.- Terms for the Quantitation of a Mixture of Stereoisomers Volker Schurig.- Differentiation of Enantiomers by Capillary Electrophoresis.- Self-disproportionation of Enantiomers of Enantiomerically Enriched Compounds.- Chiral Sensor Devices for Differentiation of Enantiomers.- Interconversion of Stereochemically Labile Enantiomers (Enantiomerization).- Chiral NMR Solvating Additives for Differentiation of Enantiomers.- Chiral Derivatizing Agents, Macrocycles, Metal Complexes, and Liquid Crystals for Enantiomer Differentiation in NMR Spectroscopy.- Enantiomeric Differentiation by Synthetic Helical Polymers.- Enantiopure supramolecular cages: synthesis and chiral recognition properties.