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Presents the wide range of carbene-transformation and its application in cross-coupling reactions, insertion reactions, asymmetric synthesis and many more.
Auteur
Jianbo Wang is Full Professor at Peking University, China. He has published more than 300 articles in peer-reviewed journals and serves as Associate Editor of Journal of Physical Organic Chemistry and Chinese Journal of Organic Chemistry. Chi-Ming Che is Dr. Hui Wai-Haan Chair of Chemistry at The University of Hong Kong (HKU) and Director of China's State Key Laboratory of Synthetic Chemistry. His honors include the China State Natural Science Award and the Centenary Prize from the Royal Society of Chemistry. Michael P. Doyle is Rita and John Feik Distinguished University Chair in Medicinal Chemistry at The University of Texas, San Antonio, TX, USA. He has received numerous awards and is the author and co-author of numerous books and more than 400 journal publications.
Résumé
Presents an up-to-date overview of the rapidly growing field of carbene transformations Carbene transformations have had an enormous impact on catalysis and organometallic chemistry. With the growth of transition metal-catalyzed carbene transformations in recent decades, carbene transformations are today an important compound class in organic synthesis as well as in the pharmaceutical and agrochemical industries. Edited by leading experts in the field, Transition Metal-Catalyzed Carbene Transformations is a thorough summary of the most recent advances in the rapidly expanding research area. This authoritative volume covers different reaction types such as ring forming reactions and rearrangement reactions, details their conditions and properties, and provides readers with accurate information on a wide range of carbene reactions. Twelve in-depth chapters address topics including carbene C-H bond insertion in alkane functionalization, the application of engineered enzymes in asymmetric carbene transfer, progress in transition-metal-catalyzed cross-coupling using carbene precursors, and more. Throughout the text, the authors highlight novel catalytic systems, transformations, and applications of transition-metal-catalyzed carbene transfer.
Contenu
INTRODUCTION
DEVELOPMENTS OF NEW CATALYSTS FOR METAL CARBENE TRANSFORMATIONS
CYCLOPROPANATIONS, CYCLOPROPENATIONS, AND RELATED REACTIONS
C-H INSERTION REACTIONS WITH CARBENE
HETEROATOM-HYDROGEN INSERTIONS WITH CARBENE
YLIDE FORMATION AND RELATED REACTIONS
CARBENE DIMERIZATION FOR OLEFIN SYNTHESIS
TRANSITION-METAL-CATALYZED CROSS-COUPLING WITH CARBENE
TRANSITION-METAL-CATALYZED TRANSFORMATION WITH VINYL DIAZOACETATES
TRANSITION-METAL-CATALYZED CARBENE TRANSFER IN POLYMERIZATION
APPLICATION OF TRANSITION-METAL-CATALYZED REACTIONS IN TOTAL SYNTHESIS
TRANSITION-METAL-CATALYZED CARBENE TRANSFER REACTION IN FLOW CHEMISTRY