Advanced Structural Chemistry

Diese einzigartige Publikation beschäftigt sich mit der Beziehung zwischen Struktur und Funktion von Stoffen, wirkungsvollen und präzisen Synthesemethoden und theoretischen Werkzeugen für neue Funktionscluster und poröse Materialien.

Auteur

*Rong Cao, PhD, is Director of the Fujian Institute of Research on the Structure of Matter (FJIRM) and Director of the Institute of Urban Environment at the Chinese Academy of Sciences (CAS). He received his doctorate in Chemical Physics from the FJIRM, CAS. He is the recipient of multiple awards, including the China Youth Science and Technology Award and the National Candidate of New Century Talents Project in 2006.*

Résumé
Advanced Structural Chemistry Discover the relationships between inorganic chemical synthesis, structure, and property with these comprehensive and insightful volumes*Advanced Structural Chemistry: Tailoring Properties of Inorganic Materials and their Applications (3 Volume Set) offers readers the opportunity to discover the relationship between the structure and function of matter, develop efficient and precise synthesis methodology, and to understand the theoretical tools for new functional substances.*Advanced Structural Chemistry clarifies the relationships between synthesis and structure, as well as structure and property, both of which are central to the creation of new materials with unique functions. In addition to subjects like the syntheses of metal-oxide clusters, metal-organic cages, and metal-organic frameworks with tailored optical, electric, ferroelectric, magnetic, adsorption, separation, and catalytic properties, the accomplished editor Rong Cao provides readers with information on a wide variety of topics, such as:

• Coordination-assembled metal-organic macrocycles and cages, including metallacycles and metallacages
• The structural chemistry of metal-oxo clusters, including the oxo clusters of transition metal, main group metal, and lanthanides
• Synthetic approaches, structural diversities, and biological aspects of molybdenum-based heterometallic sulfide clusters and coordination polymers
• Group 11-15 metal chalcogenides, including discrete chalcogenide clusters synthesized in ionic liquids
• The structures of metal-organic frameworks, including one-, two-, and three-dimensional MOFsPerfect for inorganic chemists, structural chemists, solid state chemists, material scientists, and solid state physicists, Advanced Structural Chemistry also belongs on the bookshelves of catalytic and industrial chemists who seek to improve their understanding of the structure and functions of inorganic materials.

Contenu
Volume 1

**1 Introduction 1
**Jian Zhang, Guo-Cong Guo, Rong Cao, and Xin-Tao Wu

**2 Coordination-Assembled MetalOrganic Macrocycles and Cages 9
**Xiao-Zhen Li, Yu-Ling Liang, Li-Peng Zhou, Li-Xuan Cai, Qiang-Yu Zhu, Zhuo Wang, Xiao-Qing Guo, Dan-Ni Yan, Shao-Jun Hu, Shao-Chuan Li, Shi-Yu Wu, Shi-Long Han, Ran Chen, Pei-Ming Cheng, Kai Cheng, Xiao-Shan Feng, Tian-Pu Sheng, Can He, Feng-Rong Dai, and Qing-Fu Sun

2.1 Introduction 9

2.2 Metallacycles 9

2.2.1 Dinuclear Metallamacrocycles 10

2.2.2 Triangles 10

2.2.3 Rectangle 12

2.2.4 Hexagons 14

2.2.5 Irregular Metallacycles 20

2.2.6 Multilayered Metallacycles 22

2.2.7 Polygon-Based Polymers 28

2.2.8 Responsive Dynamic Metallacycles 34

2.3 Metallacages 35

2.3.1 Helicates 35

2.3.2 Tetrahedron 38

2.3.3 Truncated Tetrahedron 46

2.3.4 Triangular Prism 47

2.3.5 Cubes 50

2.3.6 Octahedron 54

2.3.7 Dodecahedron 61

2.3.8 Cuboctahedrons 65

2.3.9 Hexadecahedrons 65

2.3.10 Barrel-Shaped Cages 67

2.3.10.1 Calixarene Constructed Barrel-Shaped Cages 67

2.3.10.2 Dimetallic Clips-Constructed Barrel-Shaped Cages 68

2.3.11 Multiple Structural Cages 71

2.3.12 Other Cages 74

2.4 Conclusion 77

Acknowledgments 77

References 77

**3 Structural Chemistry of Metal-Oxo Clusters 81
**Xiaofeng Yi, Weihui Fang, Jinying Liu, Cheng Chen, Mingyan Wu, and Lei Zhang

3.1 Oxo Clusters of Transition Metal 81

3.1.1 Introduction 81

3.1.2 General Synthetic Approaches and Experimental Methods 83

3.1.2.1 General Synthetic Approaches 83

3.1.2.2 Experimental Methods 83

3.1.3 Polyoxotitanates (POTis) 84

3.1.3.1 Diverse Structures of POTis 84

3.1.3.2 Tuneable Properties of POTis: Bandgap Engineering and Photo-Related Activities 89

3.1.3.3 Potential Application of POTis 92

3.1.4 Polyoxovanadates (POVs) 95

3.1.4.1 Diverse Structure of POVs 95

3.1.4.2 Tunable Properties and Potential Applications of POVs 101

3.1.5 Polyoxoniobates (PONbs) 102

3.1.6 Polyoxomolybdates (POMos) 104

3.1.7 Polyoxopalladates (POPs) 105

3.1.8 Polyoxotungstates (POTs) 107

3.1.8.1 Transition-Metals-Substituted-POTs (TMSPs) 107

3.1.8.2 InorganicOrganic Hybrid TMSPs 107

3.1.9 Polyoxotantalates (POTas) 109

3.2 Oxo Clusters of Main Group Metal 111

3.2.1 Introduction 111

3.2.2 Synthesis of Borates 111

3.2.2.1 Inorganic Templated Borates 112

3.2.2.2 Organic-Templated Borates 113

3.2.2.3 TMC-Templated Borates 113

3.2.2.4 Templated Synthesis of Aluminoborates 115

3.2.3 Synthesis of Germinates and Borogermanates 116

3.2.3.1 Templated Synthesis of Germinates 116

3.2.3.2 Templated Synthesis of Germinates 117

3.2.3.3 Self-Polymerization and Induced Congregation of Lanthanide Germanate Lusters 118

3.2.4 Aluminum Oxo Clusters Hydrolysis and Condensation 119

3.2.4.1 Aluminum Oxo Clusters Isolated from Organic Solutions 119

3.2.4.2 Aluminum Oxo Clusters Via Aqueous Synthetic Routes 120

3.3 Oxo Clusters of Lanthanides 122

3.3.1 Introduction 122

3.3.2 High-Nuclearity Clusters of Lanthanides 123

3.3.2.1 High-Nuclearity Lanthanide Clusters Supported by O-Donor Ligands 123

3.3.2.2 High-Nuclearity Lanthanide Clusters Supported by N-Donor Ligands 127

3.3.2.3 High-Nuclearity Lanthanide Clusters Supported by Multiple N,O-Donor Ligands 129

3.3.2.4 High-Nuclearity Lanthanide Clusters Supported by Calix[n]arenes Ligands 136

3.3.2.5 High-Nuclearity Lanthanide Clusters Supported by Other Donor Ligands 139

3.3.3 Monometallic Lanthanide-Based Single-Molecule Magnets 140 3.3.4 Heterometallic 3d4f Clusters 14...