Organic Chemistry in Confining Media

This book widens consideration of organic reactivity in confining media, discussing such topics as effects of micellization, porous effects, complexation to organometallic compounds, hydrogen-bond or charge-transfer complexation, sorption effects and more.

Zory Vlad Todres' monograph offers a fresh insight into an important and developed area of organic chemistry. Calixarene, cyclodextrins, and cucurbiturils as host molecules are well known, but the corresponding new and demonstrative publications deserve new exposition. This book principally widens our consideration of organic reactivity in confining media. Topics discussed include: effects of micellization, porous effects, effects of solvent cages, complexation to organometallic compounds, hydrogen-bond or charge-transfer complexation, sorption effects, effects of solvents, and stereochemical changes upon confinement. Organic Chemistry in Confining Media is useful for experienced organic chemists working in academia or industry, as well as chemists working in fields contiguous to organic chemistry.

Includes lesser discussed topics such as transformations within micelles, porous materials, solvent cages, hydrogen-bond or charge-transfer complexes

Addresses practical applications of the confinement effects

Widens the discussion on confinement effects in chemistry

Includes supplementary material: sn.pub/extras

Auteur
Zory Vlad Todres holds a Ph.D. in chemical technology and Sc.D. (a doctor habilitatus) in physical organic chemistry. He has published several hundred papers on electron- and charge-transfer phenomena, on metal-coordination assemblage and on reactions of organic substrates influenced by sorption. Previously, he has published the following books: "Organic Ion-Radicals", Chalcogenadiazoles, "Organic Mechanochemistry", and "Ion-Radical Organic Chemistry". With his books, Z.V. Todres aspires to engraft new and practically important branches to the great tree of organic chemistry. The proposed book on confined effects in organic chemistry is also a step to this direction. His published books are much in demand and have been well-received by the chemical community.

Contenu

Encapsulation effects: Calixarene hosts, Concaves as hosts, Carcerands as hosts, Cyclodextrin hosts, Cucurbituril hosts, Tweezers-like hosts.- Resin-docking, surface-bound and polymer-penetration effects.- Reactions within charge-transfer complexes.- Effects of hydrogen bonding.- Effects of coordination to metals: Organic ligand isomerization within metallocomplexes, Metal-coordination assemblage.- Effects of sorption.- Micellar effects.- Solvent-cage effects.- Crystal porous, microporous and mesoporous effects.- Stereochemical outcomes of confinement: Guest-confinement effects on host configurations, Host-confinement effects on guest configurations.- Solvent role in confined organic reactions.