Polymer Photodegradation

During the last two decades, the production of polymers and plastics has been increasing rapidly. In spite of developing new polymers and polymeric materials, only 40~60 are used commercially on a large scale. It has been estimated that half of the annual production of polymers is employed outdoors. The photochemical instability of most polymers limits their outdoor application as they are photodegraded quickly over periods from months to a few years. To the despair of technologists and consumers alike, photodegradation and environmental ageing of polymers occur much faster than can be expected from knowledge collected in laboratories. In order to improve polymer photostability there has been a very big effort during the last 30 years to understand the mechanisms involved in photodegradation and environmental ageing. This book represents the author's attempt, based on his 25 years' experience in research on photodegradation and photo stabilization, to collect and generalize a number of available data on the photodegradation of polymers. The space limitation and the tremendous number of publications in the past two decades have made a detailed presentation of all important results and data difficult. The author apologizes to those whose work has not been quoted or widely presented in this book. Because many published results are very often contradictory, it has been difficult to present a fully critical review of collected knowledge, without antagonizing authors. For that reason, all available theories, mechanisms and different suggestions have been presented together, and only practice can evaluate which of them are valid.

Contenu
Physical aspects of the photodegradation of polymers. Photochemical aspects of degradation of polymers. Photodegradation and photo-oxidative degradation of homochain polymers. Photodegradation and photo-oxidative degradation of heterochain polymers. Role of metal compounds in the photodegradation of polymers. Degradation of polymers initiated by radicals formed from photolysis of different compounds. Degradation of polymers by oxygen reactive species formed from photoreactions of oxygen. Photodegradable polymers. Photodegradation of polymers in extreme conditions. Experimental methods in polymer degradation. References. Index.