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Homogeneous Hydrogenation

  • Kartonierter Einband
  • 304 Seiten
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Homogeneous hydrogenation is one of the most thoroughly studied fields of homogeneous catalysis. The results of these studies have... Weiterlesen
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Homogeneous hydrogenation is one of the most thoroughly studied fields of homogeneous catalysis. The results of these studies have proved to be most important for an understanding of the underlying principles of the activation of small molecules by transition metal complexes. During the past three decades homogeneous hydrogenation has found widespread application in organic chemistry, including the production of important pharmaceuticals, especially where a sophisticated degree of selectivity is required.
This volume presents a general account of the main principles and applications of homogeneous hydrogenation by transition metal complexes. Special attention is devoted to the mechanisms by which these processes occur, and the role of the recently discovered complexes of molecular hydrogen is described. Sources of hydrogen, other than H2, are also considered (transfer hydrogenation). The latest achievements in highly stereoselective hydrogenations have made possible many new applications in organic synthesis. These applications are documented by giving details of the reduction of important unsaturated substrates (alkenes, alkynes, aldehydes and ketones, nitrocompounds, etc.). Hydrogenation in biphasic and phase transfer catalyzed systems is also described. Finally, a discussion of the biochemical routes of H2 activation highlights the similarities and differences in performing hydrogenation in both natural and synthetic systems.
For researchers working in the fields of homogeneous catalysis, especially in areas such as pharmaceuticals, plastics and fine chemicals.

The Mechanisms of Homogeneous Hydrogenation. Homogeneous Transfer Hydrogenation Catalyzed by Metal Complexes. Homogeneous Hydrogenation in Organic Synthesis. Hydrogenation in Aqueous Systems. Hydrogen Activation in Biological Systems. Index.


Titel: Homogeneous Hydrogenation
EAN: 9789048143238
ISBN: 9048143233
Format: Kartonierter Einband
Herausgeber: Springer Netherlands
Anzahl Seiten: 304
Gewicht: 746g
Größe: H279mm x B210mm x T16mm
Jahr: 2010
Untertitel: Englisch
Auflage: Softcover reprint of hardcover 1st ed. 1994

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