There is a certain fascination associated with words. The manipulation of strings of symbols according to mutually accepted rules allows a language to express history as well as to formulate challenges for the future. But language changes as old words are used in a new context and new words are created to describe changing situations. How many words has the computer revolution alone added to languages? "Inorganometallic" is a word you probably have never encountered before. It is one created from old words to express a new presence. A strange sounding word, it is also a term fraught with internal contradiction caused by the accepted meanings of its constituent parts. "In organic" is the name of a discipline of chemistry while "metallic" refers to a set of elements constituting a subsection of that discipline. Why then this Carrollian approach to entitling a set of serious academic papers? Organic, the acknowledged doyenne of chemistry, is distinguished from her brother, inorganic, by the prefix "in," i. e. , he gets everything not organic. Organometallic refers to compounds with carbon-metal bonds. It is simple! Inorganometallic is everything else, i. e. , compounds with noncarbon-metal element bonds. But why a new term? Is not inorganic sufficient? By virtue of training, limited time, resources, co-workers, and so on, chemists tend to work on a specific element class, on a particular compound type, or in a particular phase. Thus, one finds element-oriented chemists (e. g.

Klappentext

The contributors to this volume summarize recent discoveries in the theory, structure, and reactivity of compounds with noncarbon--metal bonds and suggest directions for the future exploration of this growing field.

Inhalt

1. Introduction.- 2. Main Group Fragments as Ligands to Transition Metals.- 3. Transition Metal-Main Group Cluster Compounds.- 4. Bonding Connections and Interrelationships.- 5. Experimental Comparison of the Bonding in Inorganometallic and Organometallic Complexes by Photoelectron Spectroscopy.- 6. Transition Metal-Promoted Reactions of Main Group Species and Main Group-Promoted Reactions of Transition Metal Species.- 7. The Metal-Nonmetal Bond in the Solid State.- 8. Molecular Precursors to Thin Films.- 9. Ceramics.