David I.A. Millar's thesis explores the effects of extreme conditions on energetic materials. His study identifies and structurally characterises new polymorphs obtained at high pressures and/or temperatures. The performance of energetic materials (pyrotechnics, propellants and explosives) can depend on a number of factors including sensitivity to detonation, detonation velocity, and chemical and thermal stability. Polymorphism and solid-state phase transitions may therefore have significant consequences for the performance and safety of energetic materials. In order to model the behaviour of these important materials effectively under operational conditions it is essential to obtain detailed structural information at a range of temperatures and pressures.

Nominated by the University of Edinburgh for a Springer Theses Prize Introductory chapters are an excellent way into high -pressure research and energetic materials for newcomers to the field Highly developed critical analysis and outline of opportunites for further research Includes supplementary material: sn.pub/extras

Inhalt
Introduction.- Experimental Techniques.- Structural Studies of RDX.- High-Pressure Structural Studies of CL-20.- Structural Investigation of a Series of Inorganic Azides (Part 1).- Structural Investigation of a Series of Inorganic Azides (Part 2).- General Remarks.