The solutions manual to accompany Organic Chemistry provides fully-explained solutions to all the problems that feature in the second edition of Organic Chemistry . Intended for students and instructors alike, the manual provides helpful comments and friendly advice to aid understanding, and is an invaluable resource wherever Organic Chemistry is used for teaching and learning.

Autorentext

Jonathan Clayden, University of Manchester;Stuart Warren, University of Cambridge

Inhalt

• 1: What is organic chemistry?

• 2: Organic structures

• 3: Determining organic structures

• 4: Structure of molecules

• 5: Organic reactions

• 6: Nucleophilic addition to the carbonyl group

• 7: Delocalization and conjugation

• 8: Acidity, basicity, and pKa

• 9: Using organometallic reagents to make C-C bonds

• 10: Nucleophilic substitution at the carbonyl group

• 11: Nucleophilic substitution at C=O with loss of carbonyl oxygen

• 12: Equilibria, rates and mechanisms

• 13: 1H NMR: Proton nuclear magnetic resonance

• 14: Stereochemistry

• 15: Nucleophilic substitution at saturated carbon

• 16: Conformational analysis

• 17: Elimination reactions

• 18: Review of spectroscopic methods

• 19: Electrophilic addition to alkenes

• 20: Formation and reactions of enols and enolates

• 21: Electrophilic aromatic substitution

• 22: Conjugate addition and nucleophilic aromatic substitution

• 23: Chemoselectivity and protecting groups

• 24: Regioselectivity

• 25: Alkylation of enolates

• 26: Reactions of enolates with carbonyl compounds: the aldol and Claisen reactions

• 27: Sulfur, silicon and phosphorus in organic chemistry

• 28: Retrosynthetic analysis

• 29: Aromatic heterocycles 1: structures and reactions

• 30: Aromatic heterocycles 2: synthesis

• 31: Saturated heterocycles and stereoelectronics

• 32: Stereoselectivity in cyclic molecules

• 33: Diastereoselectivity

• 34: Pericyclic reactions 1: cycloadditions

• 35: Pericyclic reactions 2: sigmatropic and electrocyclic reactions

• 36: Participation, rearrangement and fragmentation

• 37: Radical reactions

• 38: Synthesis and reactions of carbenes

• 39: Determining reaction mechanisms

• 40: Organometallic chemistry

• 41: Asymmetric synthesis

• 42: Organic chemistry of life

• 43: Organic chemistry today