This monograph develops a unified microscopic basis for phases and phase changes of bulk matter and small systems, in terms of classical physics. It describes the thermodynamics of ensembles of particles and explains phase transition in gaseous and liquid systems. The origins of such phase changes are derived from simple but physically relevant models of how transitions occur between rigid and fluid states, of how phase equilibria arise, and how they differ for small and large systems.

Describes the thermodynamics of ensembles of particles Explains phase transition in gaseous and liquid systems Both a reference book for researchers and a textbook for students Includes supplementary material: sn.pub/extras

Autorentext

V.P. Krainov was born in Moscow in 1938. In 1962 he obtained a Master of Science in the field of theoretical nuclear physics and went on to complete his Doctor of Phys. Mat. Science in 1982. He became a professor of physics in 1986. Between 1963 and 1971 he worked as a scientist at the Kurchatov Institute of Atomic Energy in Moscow and was a professor at the Moscow Engineering Physics Institute from 1971 to 1992. Since then he has been a professor at Moscow Institute of Physics and Technology. Throughout his career his research has focused primarily on the theory of atomic, molecular, plasma and nuclear physics. He is the author of 27 books and about 380 papers. Boris Smirnov was born in 1938 in Moscow. In 1962 he graduated from Moscow's Engineering-Physical Institute in theoretical nuclear physics and obtained his Doctor of Phys. Mat. Science in 1968. He became a professor of physics in 1970. Between 1962 and 1982 he was Head of Laboratory at Kurchatov Institute of Atomic Energy (Moscow), then from 1982 to 1986 Head of Laboratory at Institute of Thermophysics (Novosibirsk) and from 1986 Head of Laboratory and Head of Department and, currently, Principal Scientist at the Joint Institute for High Temperatures of the Russian Academy of Science. B.M. Smirnov was a member of the editorial board of several journals of various publishers. He was a professor at the Moscow Power Institute, Novosibirsk, State University and the Moscow Institute of Science and Technology, and is a laureate of the National Prize of Russia. His research focusses on theoretical physics, atomic, molecular, cluster, plasma and chemical physics. He is the author of 53 books and about 500 papers.

Inhalt
Thermodynamics of Ensembles of Classical Particles.- Excitations in Simple Atomic Ensembles.- Structures of Ensembles of Interacting Particles.- Thermodynamics of Dense Gases and Liquids.- Clusters with Short-Range Interaction.- Ensembles of Classical Particles with Repulsion.- Configurational Excitations and Aggregate States of Ensembles of Classical Particles.- Configurational Excitation and Voids in Ensembles of Bound Classical Atoms.- Configurational Cluster Excitation with Pairwise Interactions.- Phase Transitions in Macroscopic Systems of Atoms.- Melting of Clusters and Bulk Atomic Ensembles.- Dynamics of Configurational Excitations in Ensembles of Classical Particles.- Coexistence of Cluster Phases.- Glassy States of an Ensemble of Bound Atoms.- Transport of Voids in Nucleation Processes.- Conclusion and Summary.