As 2019 has been declared the International Year of the Periodic Table, it is appropriate that Structure and Bonding marks this anniversary with two special volumes.

In 1869 Dmitri Ivanovitch Mendeleev first proposed his periodic table of the elements. He is given the major credit for proposing the conceptual framework used by chemists to systematically inter-relate the chemical properties of the elements. However, the concept of periodicity evolved in distinct stages and was the culmination of work by other chemists over several decades. For example, Newland's Law of Octaves marked an important step in the evolution of the periodic system since it represented the first clear statement that the properties of the elements repeated after intervals of 8. Mendeleev's predictions demonstrated in an impressive manner how the periodic table could be used to predict the occurrence and properties of new elements. Not all of his many predictions proved to be valid, but the discovery ofscandium, gallium and germanium represented sufficient vindication of its utility and they cemented its enduring influence. Mendeleev's periodic table was based on the atomic weights of the elements and it was another 50 years before Moseley established that it was the atomic number of the elements, that was the fundamental parameter and this led to the prediction of further elements.

Some have suggested that the periodic table is one of the most fruitful ideas in modern science and that it is comparable to Darwin's theory of evolution by natural selection, proposed at approximately the same time. There is no doubt that the periodic table occupies a central position in chemistry. In its modern form it is reproduced in most undergraduate inorganic textbooks and is present in almost every chemistry lecture room and classroom.

This second volume provides chemists with an overview of the important role played by the Periodic Table in advancing our knowledge of solidstate and bioinorganic chemistry. It also illustrates how it has been used to fine-tune the properties of compounds which have found commercial applications in catalysis, electronics, ceramics and in medicinal chemistry.

Autorentext

Michael Mingos was born in Basra, Iraq in 1944 and was educated in England (Manchester, B.Sc. in Chemistry 1965) and University of Sussex (D.Phil, 1968). He has held academic posts at QMC, Oxford (Keble College), Imperial College, St Edmund Hall (Principal,1999-2009). His theoretical research has resulted in generalisations which have greatly influenced the development and teaching of modern inorganic chemistry. Specifically the Wade-Mingos Rules which rationalise the structures of polyhedral inorganic molecules and the Green-Davies-Mingos Rules, which account for some of the nucleophilic reactions of organometallic compounds. His group has experimentally verified some of his theoretical predictions, for example an icosahedral molecule containing gold atoms -which is relevant for understanding the metal's nano-technological possibilities. He has also contributed to the understanding of the bonding properties of nitric oxide, an important cellular signalling molecule involved in many physiological processes and pioneered the acceleration of chemical reactions using microwave energy. He was elected the Royal Society in 1992 and the European Academy of Sciences in 2017. He holds honorary doctorates from Sussex and Manchester Universities and received many prizes - the most recent was the Blaise Pascal Medal in 2017

Inhalt

The Renaissance of Base Metal Catalysis enabled by Functional Ligands.- The Periodic Table, Zeolites and Single-Site Heterogeneous Catalysts.- Synthesis and properties of zeolites guided by periodic considerations.- The Periodic Table as a Guide to the Construction and Properties of Layered Double Hydroxides.- Perovskite, A Solid State Chameleon: Illustrating Elements, their Properties and Location in the Periodic Table.- The Periodic Table's Impact on Bio-inorganic Chemistry and Biology's selective use of metal ions.- A Periodic Table for Life and Medicines.- Interactions between metal ions and DNA.