This book presents and analyzes the influence of small size particles of lead, cadmium and silver sulfide on the properties of nonstoichiometric semiconductors. Important nonstoichiometry aspects in nanostructures are discussed, such as the distribution of sulfur atoms in nanofilms, a non-periodic distribution of the atomic planes in nanoparticles, interdependent changes in crystal structure of nanocrystalline material. Tuning the stoichiometry allows to obtain superionic conductivity and catalytic activity under visible light. The wavelength of the luminescence of nanoparticles changes with the size of the nanoparticles. Various methods to prepare nanostructured sulfides are described. Special attention is given to the hydrochemical bath deposition as a universal method for the synthesis of sulfides as nanofilms, stable colloidal solutions, quantum dots, isolated nanoparticles with a protective shell and heteronanostructures. The effect of nanoparticle size and nonstoichiometry onthe band gap, optical and thermal properties of nanostructured sulfides is also considered. The novel applications of sulfide nanoparticles in nanoelectronics, catalysis, nanobiology and nanomedicine are sketched.

Autorentext

Dr. Stanislav I. Sadovnikov is currently a senior research scientist in the Laboratory of nonstoichiometric compounds of the Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences. He has studied the synthesis, structure and properties of nanostructured semiconducting sulfides for more than 10 years and is a recognized expert in the field of nanosized sulfide synthesis. He is an author of two review articles and more than 60 scientific articles.

Prof. Dr. Aleksandr I. Gusev is chief research scientist of the Laboratory of nonstoichiometric compounds in the Institute of Solid State Chemistry of the Russian Academy of Sciences. He has been exploring crystal and electronic structure and properties of novel nonstoichiometric compounds including carbides, sulfides, and oxides, and nanostructured advanced materials for more than 40 years. He is the author of 16 monographs including Disorder and Order in Strongly Nonstoichiometric Compounds, Springer (2001), Nanocrystalline Materials, Cambridge (2004), Tungsten Carbides: Structure, Properties and Application in Hardmetals, Springer (2013), 23 reviews articles and more than 250 scientific articles.

Prof. Dr. Andrey A. Rempel is a head of the Laboratory of nonstoichiometric compounds of the Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences. His current research interests are solid state physics, theory of phase transformations, atomic ordering in strongly nonstoichiometric compounds, nonstoichiometry and atomic defects in nanocrystalline substances including carbides, oxides, and sulfides. He is author of 10 monographs in English and Russian, 11 review articles and more than 200 scientific publications.

Inhalt
Preface.- Size Characterization of Nanostructured Materials.- Concept of Nanostructured Material.- Methods of Evaluation of the Size of Small Particles.- Nanostructured Lead Sulfide PbS.- Methods for the Preparation of Nanostructured Lead Sulfide: From Colloidal Solutions to Thin Films.- Crystal Structures of Nanoparticles, Nanopowders, and Nanofilms of Lead Sulfide.- Properties of Nanostructured Lead Sulfide .- Application of Nanostructured Lead Sulfide .- Nanostructured Cadmium Sulfide CdS.- Chemical Deposition of Nanostructured Cadmium Sulfide CdS.- Synthesis of CdS Nanoparticles in Glass Matrix.- Features of Crystal Structure of CdS Nanoparticles.- Optical Properties of Nanostructured CdS.- Nanostructured Silver Sulfide Ag2S.- Methods of Synthesis of Nanostructured Silver Sulfide Ag2S.- Crystal Structure of Coarse-Crystalline and Nanostructured Ag2S Silver Sulfide.- Universal Approach to Synthesis of Silver Sulfide in the Form of Nanopowders, Quantum Dots, Core-Shell Nanoparticles, and Heteronanostructures.- Green Synthesis of Nanostructured Ag2S Without Hazardous Substances.- Coarse-crystalline Ag2S powders.- Deposited Ag2S Nanopowders.- Colloidal Solutions of Ag2S Quantum Dots.- Core-Shell Ag2S@C Nanoparticles.- Ag2S/Ag heteronanostructures.- Hydrochemical Bath Deposition: Advantages and Challenges.