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Preparative Chemistry Using Supported Reagents explains a certain dimension in the methodology of organic reactions.
This book discusses the physical methods for study that characterizes surfaces and their adsorbates and chemical reactivity at interfaces. The polymer-supported reagents, shape-selectivity within zeolites, and graphite intercalates are also described. Other topics include the metal oxides and their physico-chemical properties in catalysis and synthesis; photochemistry of adsorbed molecules; and magnetic spin resonance methods and applications to oxide surfaces. The physico-chemical characterization of supported reagents; polymer-supported oxidations; and alumina and alumina-supported reagents are likewise deliberated. This text also covers the novel aluminophosphate-based molecular sieves, clay-activated isomerization reactions, anionic activation, and cationic reactions.
This publication is beneficial to chemists and researchers conducting work on supported reagents.
Inhalt
Preface
Part I Supported Reagents: General Principles
1 Homogeneous and Heterogeneous Reaction Conditions
I. The Alchemical Heritage
II. The Example of Industrial Chemistry
III. The Lessons from Chromatography
IV. The Lead from Biochemistry
V. Shifting Habits
VI. Easier Work Up
VII. Faster Reactions under Milder Conditions
VIII. Improved Selectivity
IX. Safer Reagents
X. Surface Chemistry as a New Frontier in Chemistry
References
2 Characterization of Surface Irregularity
I. Introduction
II. Notion of Fractal Dimension
III. Experimental Methods of Fractal Surface Analysis
IV. Restricted Diffusion on a Surface and Encounter of Reagents: The Effects of Dimensionality
V. Diffusion of Reagents in Pore Space
VI. Conclusions and Strategies for Supported Reactions
References