This volume discusses the great potential of metal nanoparticle catalysts for complicated molecular synthesis and reviews the current progress of this field. The development of highly active and stable heterogeneous catalysts is a crucial subject in modern science. However, development of heterogeneous catalysts for fine chemical synthesis has lagged far behind those for bulk chemical process. In recent years metal nanoparticle catalysts have been of great interest in this area due to their unique activity, ease of heterogenization, and robustness. Therefore, metal nanoparticle catalysts are an excellent candidate for the above-mentioned active and robust heterogeneous catalysts and this book provides an overview of this area. The present volume summarizes recent progress on nanoparticle catalysis for various organic transformations from simple redox reactions to complex asymmetric C-C bond forming reactions and also presents seminal studies on new technologies. It comprehensively summarizes advances in metal nanoparticle catalysis across several aspects including reaction manners, mechanistic investigations and new synthetic methodologies to encourage the use of metal nanoparticle catalysts for future organic synthesis. This volume will be of interest to students, researchers and professionals focused on the next-generation of fine chemical synthesis.

Autorentext

Professor Shu Kobayashi studied at the University of Tokyo, receiving his Ph.D. in 1988 working under the direction of Professor T. Mukaiyama. Following an initial period as assistant professor, he was promoted to lecturer then associate professor at Science University of Tokyo (SUT). In 1998, he moved to the Graduate School of Pharmaceutical Sciences, the University of Tokyo, as full professor. In 2007, he was appointed to his current position as professor of Organic Chemistry in the Department of Chemistry, Faculty of Science, at the University of Tokyo. He has held various visiting professorships, including the Universite Louis Pasteur, Strasbourg (1993), Kyoto University (1995), Nijmegen University (1996), Philipps-University of Marburg (1997) and Paris-Sud (2010). Professor Kobayashi has wide-ranging research interests that include the development of new synthetic methods and novel catalysts, organic reactions in water, solid-phase synthesis, total synthesis of biologically interesting compounds, and organometallic chemistry. He has held numerous named lectureships and is a recipient of many prestigious awards, including the Chemical Society of Japan Award for Young Chemists (1991), OMCOS Award in Organometallic Chemistry (1997), IBM Science Award (2001), Organic Reactions Lecturer (2002), Nagoya Silver Medal (2002), Mitsui Chemical Catalysis Science Award (2005), JSPS Prize (2005), the Arthur C. Cope Scholar Award from the American Chemical Society (2006), Howard Memorial Lecturer (2006), C.S. Hamilton Award (2007), Merck-Cambridge Lecturer (2007), Humboldt Research Award (2013), Green Chemistry Minister of Education Award (2013), AAAS Fellow (2015), and Toray Award (2015).

Inhalt

Gold Nanoparticles for Oxidation Reactions: Critical Role of Supports and Au Particle Size.- Metal nanoparticles for redox reactions.- Earth abundant metal nanoparticle catalysis.- Precise synthesis of nanoparticle and their catalytic behavior.- Coupling reaction and C-H activation by metal nanoparticle.- Nanoparticle catalysts in flow system.- Nanoparticle catalyst meets biochemistry.- Chiral nanoparticle for asymmetric catalysis.