An exciton is an electronic excitation wave consisting of an electron-hole pair which propagates in a nonmetallic solid. Since the pioneering research of Fren­ kel, Wannier and the Pohl group in the 1930s, a large number of experimental and theoretical studies have been made. Due to these investigations the exciton is now a well-established concept and the electronic structure has been clarified in great detail. The next subjects for investigation are, naturally, dynamical processes of excitons such as excitation, relaxation, annihilation and molecule formation and, in fact, many interesting phenomena have been disclosed by recent works. These excitonic processes have been recognized to be quite important in solid-state physics because they involve a number of basic interactions between excitons and other elementary excitations. It is the aim of this quasi monograph to describe these excitonic processes from both theoretical and experimental points of view. we take a few To discuss and illustrate the excitonic processes in solids, important and well-investigated insulating crystals as playgrounds for excitons on which they play in a manner characteristic of each material. The selection of the materials is made in such a way that they possess some unique properties of excitonic processes and are adequate to cover important interactions in which excitons are involved. In each material, excitonic processes are described in detail from the experimental side in order to show the whole story of excitons in a particular material.

Inhalt

1. Introduction.- 1.1 The Ground State of Many-Body Systems and the Modes of Excitation.- 1.2 Electronic Excitation in Insulators and the Wannier-Mott Exciton.- 1.3 The Frenkel Exciton.- 1.4 The General Case.- 1.4.1 Effective Mass Approximation.- 1.4.2 The Role of Spin.- 1.4.3 Interplay of Spin-Orbit and Exchange Interactions.- 1.4.4 Davydov Splitting.- 1.4.5 Charge Transfer Excitons.- 1.5 Optical Absorption Spectra.- 1.5.1 Allowed Edge Case.- 1.5.2 Forbidden Edge Case.- 1.5.3 Transition from Frenkel to Wannier-Mott Exciton.- 1.6 The Polariton and Spatial Dispersion.- 1.7 Scope of the Present Book.- 2. Theoretical Aspects of Excitonic Molecules.- 2.1 Fission and Fusion of Excitons vs. Chemical Reaction into Excitonic Molecules.- 2.2 The Excitonic Molecule and Electron-Hole Liquid.- 2.2.1 Binding Energy and Electronic Structure of Excitonic Molecule in a Simple System - CuX.- 2.2.2 The Metallic Droplet and Excitonic Molecule in Many-Valley Structures - Ge and Si.- 2.2.3 The Excitonic Molecule in Many-Valley Systems - TlX and AgX.- 2.2.4 Influence of the Polarizable Lattice and the Effect of Anisotropic Effective Mass - CdS and CdSe.- 2.2.5 The Direct Forbidden Exciton - Cu2O.- 2.3 Optical Response of an Excitonic Molecule.- 2.3.1 Luminescence Spectrum.- 2.3.2 Relaxation by Emission of Acoustic Phonons.- 2.3.3 Optical Conversion of Excitons into Excitonic Molecules.- 2.3.4 Giant Two-Photon Absorption.- 2.4 Coherent Optical Phenomena Due to the Excitonic Molecule.- 2.4.1 Hyper-Raman Scattering and Luminescence.- 2.4.2 Two-Polariton Scattering Due to the Excitonic Molecule.- 2.4.3 Dispersion of the Exciton Polariton and Excitonic Molecule.- 2.4.4 Four-Wave Mixing Due to the Excitonic Molecule.- 2.4.5 Phase-Conjugation by Four-Wave Mixing.- 2.5 The Excitonic Molecule at High Densities.- 2.5.1 Renormalization of the Exciton Polariton Due to the Excitonic Molecule Giant Two-Photon Absorption.- 2.5.2 Polarization Rotation Effects Due to Two-Photon Excitation of the Excitonic Molecule.- 2.5.3 Multi-Polariton Scattering Via Excitonic Molecules.- 2.5.4 Optical Bistability Due to the Excitonic Molecule.- 2.5.5 Relaxation and Bose Condensation of Excitonic Molecules.- 3. The Exciton and Excitonic Molecule in Cuprous Halides.- 3.1 Band Structure and Excitonic States.- 3.2 Exciton Absorption, Reflection, and Emission Spectra.- 3.2.1 Absorption and Reflection Spectra.- 3.2.2 Splitting of Exciton Bands by Perturbations.- 3.2.3 Emission Spectra.- 3.2.4 Phonon Structure in the Excitation Spectra of Free-Exciton Emission.- 3.2.5 Bound Excitons.- 3.2.6 CuCl-CuBr Solid Solutions.- 3.3 High-Density Excitation Effects.- 3.3.1 Exciton-Electron Interaction.- 3.3.2 Effect on Exciton Absorption Bands.- 3.3.3 Creation of the Excitonic Molecule by Exciton-Exciton Collision.- 3.4 Giant Two-Photon Excitation of the Excitonic Molecule.- 3.4.1 Evidence of Giant Two-Photon Creation.- 3.4.2 Giant Two-Photon Absorption.- 3.5 Two-Photon Resonant Raman Scattering Via the Excitonic Molecule.- 3.5.1 Backward Scattering.- 3.5.2 Forward Scattering.- 3.5.3 Scattering with Recoil of the Upper-Branch Polariton.- 3.5.4 Polarization Character - Geometrical Selection Rules.- 3.5.5 Nonlinear Change of Exciton-Polariton Dispersion Associated with the GTA.- 3.6 Acoustic-Phonon Interaction of the Excitonic Molecule.- 3.7 Coexistence of Luminescence and Raman Components in the Resonant Excitation.- 3.8 Redistribution of Excitonic Molecules Resonantly Generated by Two-Photon Excitation.- 3.8.1 Calculation of Line-Shapes of the Excitonic Molcecule Luminescence.- 3.9 Relaxation of the Excitonic Molecule Due to Intermolecular Collisions: Influence on the GTA and Secondary Emissions.- 3.9.1 Effect on the GTA Spectra.- 3.9.2 Effect on Secondary Emissions.- 3.10 Spatial Dispersion of the Exciton and Excitonic Molecule.- 3.10.1 CuCl.- 3.10.2 CuBr.- 3.11 Higher Excited States of the Excitonic Molecule.- 4. Theory of Excitons in Phonon Fields.- 4.1 Electron-Phonon Interactions.- 4.1.1 Types and Ranges of Electron-Phonon Interactions.- 4.1.2 The Polaron.- 4.1.3 Exciton-Phonon Interactions and the Form Factor.- 4.1.4 Polaron Effects of an Exciton.- 4.2 The Exciton in Spatially Fluctuating Fields.- 4.2.1 Localization Versus Delocalization.- 4.2.2 Overall Line-Shape of the Absorption Spectra.- 4.2.3 Coherent Potential Approximation for an Exciton in a Mixed Crystal and in a Phonon Field.- 4.2.4 The Urbach Rule and Exciton Localization.- 4.3 Phonon Structures in Exciton Spectra.- 4.3.1 Motional Reduction of Phonon Sidebands.- 4.3.2 Multicomponent Line-Shape Formula.- 4.3.3 The Electron-Hole Relative Motion and the Phonon Sideband of an Exciton.- 4.4 Self-Trapping.- 4.4.1 Local Stabilities of Free and Self-Trapped States.- 4.4.2 Continuum Model for Self-Trapping.- 4.4.3 Adiabatic Potentials for Self-Trapping.- 4.4.4 Effective Mass Change in the F-S Transition.- 4.4.5 Extrinsic Self-Trapping and Shallow-Deep Instability.- 4.4.6 Instabilities in the Relative Motion of a Pair of Charged Particles.- 4.4.7 Survey of Experimental Studies of Self-Trapping and Related Instabilities.- 4.5 Electron-Hole Recombination.- 4.5.1 Polariton Bottleneck.- 4.5.2 Resonant Secondary Radiation.- 4.5.3 Capture, Recombination, and Enhanced Defect Reaction Via a Deep Impurity Level in a Semiconductor.- 4.5.4 Self-Trapping and Recombination of an Exciton as a Multiphonon Process.- 4.6 Excitonic Instability and Phase Changes.- 4.6.1 t-U-S Problem.- 4.6.2 Two-Site Two-Electron System.- 4.6.3 Hückel's (4n + 2) Rule for Ring Systems.- 4.6.4 One-Dimensional Hubbard-Peierls System.- 4.6.5 Prospects.- 5. Excitons in Condensed Rare Gases.- 5.1 Electronic Structure of Condensed Rare Gases.- 5.2 Charge Carriers in Condensed Rare Gases.- 5.3 Excitons and Exciton-Phonon Interactions in Condensed Rare Gases.- 5.3.1 Exciton Absorption Spectra.- 5.3.2 Nature of Relaxed Excitons in Condensed Rare Gases.- 5.3.3 Formation of Self-Trapped Exciton Bubbles in Condensed Neon.- 5.3.4 Relaxation of Free Excitons in Photo-Excited Rare Gas Solids.- 6. Exciton-Phonon Processes in Silver Halides.- 6.1 Electronic and Lattice Properties of Silver Halides.- 6.2 Excitons and Exciton-Phonon Interactions in Silver Halides.- 6.2.1 Exciton Transitions in Pure Crystals.- 6.2.2 Exciton Transitions in Mixed Crystals.- 6.2.3 Bound-Exciton Transitions at an Isoelectronic Iodine Impurity.- 6.3 Relaxation Processes of Photo-Excited States in S…