The Chemistry of the Actinide and Transactinide Elements is the contemporary and definitive exposition of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ions and compounds from atomic number 89 (actinium) through 109 (meitnerium), the multi-volume work has specialized and authoritative chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, trace analysis,

The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavored to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work now encompasses six volumes. All chapters represent the current state of research in the chemistry of these elements and related fields.

Autorentext

• Lester R. Morss is the Program Manager for Heavy Element Chemistry at the Office of Science , U.S. Department of Energy in Germantown, Maryland, USA. He was taught actinide chemistry fbyProfessor Burris B. Cunningham, his Ph.D. mentor at the University of California, Berkeley and from 1971 to 1980 he was a member of the chemistry faculty at Rutgers University, New Brunswick, New Jersey, USA. In 1980, Dr. Morss moved to the Argonne National Laboratory (Illinois, USA), where he remained as an actinide chemist until 2002 . At all of these institutions he carried out research in the inorganic chemistry of lanthanide and actinide elements, with a focus on transuranium elements. His publications were primarily in thermochemistry and structure-bonding relationships among metals, oxides, halides, and coordination complexes. Dr. Morss has had fellowships at the University of Liege, Belgium and at the University of Hannover, Germany (von Humboldt Senior Scientist) and he is also afellow of the American Association for the Advancement of Science.

• Norman Edelstein is an emeritus Senior Scientist at the Lawrence Berkeley National Laboratory (LBNL). He started his studies in actinide chemistry with Professor Burris B. Cunningham in 1964 at LBNL (then the University of California Radiation Laboratory), USA. Following Professor Cunningham's untimely death in 1972 he became head of the actinide chemistry group and held that position until his assignment in 2000 and 2001 as temporary Program Manager for Heavy Element Chemistry at the Office of Science, U.S. Department of Energy, Germantown, Maryland, USA. His primary research interests are the optical properties, magnetic properties, and electronic structure of the actinides and lanthanides; the general, inorganic and solution chemistry of the actinides; and synchrotron radiation studies of actinides and other environmentally relevant materials. Dr. Edelstein has published over 200 papers onthese and other topics and has edited three other volumes on actinide subjects.

• Jean Fuger is Professor Emeritus at the University of Liège, Belgium, where he has taught courses in radiochemistry, analytical chemistry, and related subjects. In the early stages of his career, whilst associated with the Inter-University Institute for Nuclear Sciences (Brussels, Belgium), he made extensive stays at the University of California Radiation Laboratory, Berkeley, USA, with Professor Burris B. Cunningham, from whom he learned various microchemical techniques in actinide chemistry, with emphasis on preparative chemistry and microcalorimetry. From 1986 to 1997 he served as head of the chemistry division and later as deputy director of the European Institute for Transuranium Elements, Karlsruhe, Germany. His research interests are centered on the structural and thermodynamic properties of the lanthanides and actinides and their compounds, as well as the solution chemistry of these elements. He published about 125 papers, and 20 monographs and book chapters on these topics.

  Klappentext
  The Chemistry of the Actinide and Transactinide Elements is the contemporary and definitive exposition of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ions and compounds from atomic number 89 (actinium) through 109 (meitnerium), the multi-volume work has specialized and authoritative chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, trace analysis,

The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavored to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work now encompasses six volumes. All chapters represent the current state of research in the chemistry of these elements and related fields.

Zusammenfassung

The fourth edition of "The Chemistry of the Actinide and Transactinide Elements" comprises all chapters in volumes 1 through 5 of the third edition (published in 2006) plus a new volume 6. To remain consistent with the plan of the first edition, to provide a comprehensive and uniform treatment of the chemistry of the actinide [and transactinide] elements for both the nuclear technologist and the inorganic and physical chemist, and to be consistent with the maturity of the field, the fourth edition is organized in three parts.

The first group of chapters follows the format of the first and second editions with chapters on individual elements or groups of elements that describe and interpret their chemical properties. A chapter on the chemical properties of the transactinide elements follows. The second group, chapters 15-26, summarizes and correlates physical and chemical properties that are in general unique to the actinide elements, because most of these elements containpartially-filled shells of 5f electrons whether present as isolated atoms or ions, as metals, as compounds, or as ions in solution. The third group, chapters 27-39, focuses on specialized topics that encompass contemporary fields related to actinides in the environment, in the human body, and in storage or wastes. Two appendices at the end of volume 5 tabulate important nuclear properties of all actinide and transactinide isotopes. Volume 6 (Chapters 32 through 39) consists of new chapters that focus on actinide species in the environment, actinide waste forms, nuclear fuels, analytical chemistry of plutonium, actinide chalcogenide and hydrothermal synthesis of actinide compounds. The subject and author indices and list of contributors encompass all six volumes.

Inhalt

1. Introduction.- 2. Actinium.- 3. Thorium.- 4. Protactinium.- 5. Uranium.- 6. Neptunium.- 7. Plutonium.- 8. Americium.- 9. Curium.- 10. Berkelium.- 11. Californium.- 12. Einsteinium.- 13. Fermium, Mendelevium, Nobelium, and Lawrencium.- 14. Transactinide Elements and Future Elements.- 15. Summary and Comparison of Properties of the Actinide and Transactinide Elements.- 16. Spectra and Electronic Structures of Free Actinide Atoms and Ions.- 17. Theoretical Studies of the Electronic Structure of Compounds of the Actinide Elements.- 18. Optical Spectra and Electronic Structure.- 19. Thermodynamic Prope…