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Heterogeneous Enantioselective Hydrogenation

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  • 305 Seiten
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Heterogeneous Enantioselective Hydrogenation: Theory and Practice reviews the development of enantioselective hydrogenation react... Weiterlesen
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Beschreibung

Heterogeneous Enantioselective Hydrogenation: Theory and Practice reviews the development of enantioselective hydrogenation reaction catalysts. It looks at the first relatively ineffective catalysts right through to modern highly effective enantioselective catalytic systems, comparable in their efficiency to chiral metal complexes and enzymatic systems. The book begins with a summary of the first work on heterogeneous metal catalysts, which showed only the principal possibilities of enantioselective reactions. It then elaborates on metal catalysts which have enantioselectivities close to 100%. Finally, the practical utilization of chiral catalytic systems in processes of hydrogenation is described. The alpha- and beta-hydroxy carboxylic acid esters produced are precursors for manufacturing many synthones used for medicines as well as for monomers used for biodegradable polyesters, both of which have important practical applications.

The volume summarizes more than 800 scientific papers in the field of enantioselective catalytic hydrogenation reactions, mainly those using heterogeneous metal catalysts. It provides detailed explanations of special techniques for the preparation of effective dissymmetric catalysts which provide highly efficient catalytic systems.



Inhalt
ASYMMETRIC ADSORPTION ON MINERALS.- HETEROGENEOUS HYDROGENATION CATALYSTS BASED ON QUARTZ.- HETEROGENEOUS CATALYSTS SUPPORTED ON CHIRAL CARRIERS.- HYDROGENATION ON CATALYSTS BASED ON Ni AND BIMETALS.- ASYMMETRIC HYDROGENATION OF 2-OXOCARBOXYLIC ACID ESTERS AND UNSATURATED CARBOXYLIC ACIDS ON MODIFIED PT AND PD CATALYSTS.- ELECTROCHEMICAL ENANTIOSELECTIVE REDUCTIONS.- PRACTICAL ASYMMETRIC CATALYTIC REACTIONS.

Produktinformationen

Titel: Heterogeneous Enantioselective Hydrogenation
Untertitel: Theory and Practice
Autor:
EAN: 9781402042966
ISBN: 978-1-4020-4296-6
Format: E-Book (pdf)
Hersteller: Springer Netherlands
Herausgeber: Springer
Genre: Chemie
Veröffentlichung: 22.05.2007
Digitaler Kopierschutz: Wasserzeichen
Dateigrösse: 5.4 MB
Anzahl Seiten: 305
Jahr: 2007