Inorganic Syntheses, Volume 37

The newest volume in the authoritative Inorganic Syntheses book series provides users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely inorganic and organometallic compounds that can be used in reactions to develop new materials, drug targets, and bio-inspired chemical entities.

Auteur
Philip P. Power FRS, is Professor of Inorganic Chemistry at the University of California, Davis, CA.

Résumé

The newest volume in the authoritative Inorganic Syntheses book series provides users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely inorganic and organometallic compounds that can be used in reactions to develop new materials, drug targets, and bio-inspired chemical entities.

Contenu

Note to Contributors and Checkers xv

Toxic Substances and Laboratory Hazards xvii

Preface xix

Chapter One DIVALENT MANGANESE, IRON, AND COBALT BIS(TRIMETHYLSILYL)AMIDO DERIVATIVES AND THEIR TETRAHYDROFURAN COMPLEXES 1

1. Introduction 1

2. Bis{bis(trimethylsilyl)amido}iron(II) dimer: [Fe{N(SiMe3)2}2]2 4

A. Bis{bis(trimethylsilyl)amido}iron(II) dimer: [Fe{N(SiMe3)2}2]2 5

3. Bis{bis(trimethylsilyl)amido}cobalt(II) dimer, [Co{N(SiMe3)2}2]2,and bis{bis(trimethylsilyl)amido}(tetrahydrofuran)cobalt(II),Co{N(SiMe3)2}2(THF) 7

A. Bis{bis(trimethylsilyl)amido}cobalt(II) dimer: [Co{N(SiMe3)2}2]2 . 8

B. Bis{bis(trimethylsilyl)amido}(tetrahydrofuran)cobalt(II): Co{N(SiMe3)2}2(THF) 9

4. Bis{bis(trimethylsilyl)amido}manganese(II) dimer, [Mn{N(SiMe3)2}2]2, and its THF complexes Mn{N(SiMe3)2}2(THF) and Mn{N(SiMe3)2}2(THF)2 10

A. Bis{bis(trimethylsilyl)amido}(tetrahydrofuran)manganese(II),Mn{N(SiMe3)2}2(THF), and bis{bis(trimethylsilyl)amido} manganese(II) dimer, [Mn{N(SiMe3)2}2]2 11

B. Bis{bis(trimethylsilyl)amido}bis(tetrahydrofuran)manganese(II) 12

C. An alternative synthesis of Mn{N(SiMe3)2}2(THF) and [Mn{N(SiMe3)2}2]2 12

Chapter Two CALCIUM, STRONTIUM, GERMANIUM, TIN, AND LEAD BIS(TRIMETHYLSILYL)AMIDO DERIVATIVES AND 2,2,6,6- TETRAMETHYLPIPERIDIDO AND N-ISOPROPYLPHENYLAMIDO DERVATIVES OF POTASSIUM AND CALCIUM 15

1. Introduction 15

2. Potassium (2,2,6,6-tetramethylpiperidide), bis(2,2,6,6- tetramethylpiperidido) (N,N,N',N' -tetramethylethylenediamine)calcium(II), potassium (N-isopropylanilido), and bis(N-isopropylanilido) Tris (tetrahydrofuran)calcium(II) 18

A. Potassium 2,2,6,6-tetramethylpiperidide 19

B. Diiodotetrakis(tetrahydrofuran)calcium(II) 20

C. Bis(2,2,6,6-tetramethylpiperidido)(N,N,N',N'- tetramethylethylenediamine)calcium(II) 20

D. Potassium N-{isopropyl(phenyl)amide} (Potassium N-isopropylanilide) 21

E. Bis{N-isopropyl(phenyl)amido}tris(tetrahydrofuran)calcium(II) 22

F. Bis[{bis(tetrahydrofuran)potassium}bis{-N(isopropyl)(phenyl) amido}]calcium(II) 22

3. Bis{bis(trimethylsilyl)amido}calcium(II) dimer, [Ca{N(SiMe3)2}2]2, and bis {bis(trimethylsilyl)amido}strontium(II) dimer, [Sr{N(SiMe3)2}2]2 24

A. Bis{bis(trimethylsilyl)amido}calcium(II) dimer, [Ca{N(SiMe3)2}2]2,and bis{bis(trimethylsilyl)amido}strontium(II) dimer, [Sr{N(SiMe3)2}2]2 25

4. Divalent Group 14 metal bis(trimethylsilylamides), M{N(SiMe3)2}2 (M = Ge, Sn, Pb) 26

A. Bis{bis(trimethylsilyl)amido}germanium(II), Ge{N(SiMe3)2}2 27

B. Bis{bis(trimethylsilyl)amido}tin(II), Sn{N(SiMe3)2}2 28 C. Bis{bis(trimethylsilyl)amido}lead(II), Pb{N(SiMe<sub&...