Redistribution Reactions

Redistribution Reactions is a comprehensive coverage of redistribution phenomena for the entire Periodic Table. This book is organized into two sections encompassing 10 chapters that tackle the concepts of structural reorganization.
Part I provides first an overview of redistribution reactions, followed by a discussion on a series of techniques capable of detecting all compounds in a redistribution reaction, including electronic, vibrational, and nuclear magnetic spectroscopy, X-ray crystallography, mass spectroscopy, polarography, chromatography, and the use of phase diagram. Part II is devoted to the redistribution reactions of the elements under Periodic Group headings with available kinetics or thermodynamics information. This part also presents valuable structural information of the group elements, such as their vibrational frequencies and chemical shifts.
This work will be of convenient reference for researchers already working on redistribution and for a more general range of research workers in inorganic chemistry who require information on scrambling for a specific element.

Contenu

Preface
Conversion Table
Part I

1. Introduction
   References
2. Experimental Techniques
   I. Spectroscopy
   II. X-Ray Crystallography
   III. Mass Spectrometry
   IV. Polarography
   V. Gas Chromatography
   VI. Phase Diagrams
   VII. Use of Labels
   References
   Part II
3. Group I
   I. Lithium Alkyls, Aryls, and Silyls
   II. Alkali ß-Diketonates
4. Group II
   I. Beryllium
   II. Magnesium
   III. Zinc
   IV. Cadmium
   V. Mercury
   VI. Exchange of Mixtures of Group II and Other Elements
   References
5. Transition Metals
   I. Carbonyls
   II. Dithiolates, Salicylaldiminates, and Aminotroponiminates
   III. ß-Diketonates
   IV. Miscellaneous Ligands
   References
6. Group III
   I. Boron
   II. Aluminum
   III. Gallium, Indium, and Thallium
   References
7. Group IV
   I. Silicon
   II. Germanium
   III. Tin
   IV. Scrambling between Group IV and Other Central Atoms
   References
8. Group V
   I. Phosphorus
   II. Arsenic
   III. Nitrogen, Antimony, and Bismuth
   References
9. Group VI
   I. Sulfur
   II. Selenium, Tellurium, Polonium, and Mixtures
10. Trends in Redistribution Reactions
    Spinoff
    References
    Author Index
    Subject Index