Informationen zum Autor Anne-Marie Caminade is Director of Research at the Centre National de la Recherche Scientifique (CNRS) in the Laboratoire de Chimie de Coordination in Toulouse (France), where she has been head of the Molecular, Macromolecular, and Supramolecular Main Group Chemistry team (15 to 20 researchers) since 2006. Having received two Ph.Ds (1984 and 1988 in Toulouse) and two Post-docs, in industry (Institut Français du Pétrole, France, 1984) and as an Alexander von Humboldt Fellow at the University of Saarbrücken (Germany, 1988), she has been working since 1985 at the CNRS in Toulouse. Her current research interest is on the synthesis, reactivity and study of properties and applications of dendrimers and dendritic macromolecules in three main fields: Catalysis, Biology-Medicine, and Materials. She is the co-author of 278 publications and 25 patents. She is the coordinator or "scientist in charge" of several French and European projects, and received the bronze medal of the CNRS in 1989, and the Organic Chemistry Prize of the French Chemical Society in 2006. Co-authors for the book will be members of her research team including: Dr Cédric-Olivier Turrin (biology), Dr Régis Laurent and Dr Armelle Ouali (catalysis), Dr Béatrice Delavaux-Nicot (materials). Klappentext This book will be mainly focussed on the properties and uses of dendrimers and dendrons. The aim of this book is to be the reference book about dendrimers applications. It will not describe all details, but it will give the reader a unique overview of what has currently been done with dendrimers, with numerous references and illustrations. It will be divided in four main parts: Part 1) Generalities, syntheses, characterizations and properties; Part 2) Applications in catalysis; Part 3) Applications for the elaboration or modification of materials; and Part 4) Applications in biology/medicine. The role of the nanometric size and the multiple functions of dendrimers on the properties will be emphasized. Zusammenfassung This book will be mainly focussed on the properties and uses of dendrimers and dendrons. The aim of this book is to be the reference book about dendrimers applications. It will not describe all details, but it will give the reader a unique overview of what has currently been done with dendrimers, with numerous references and illustrations. It will be divided in four main parts: Part 1) Generalities, syntheses, characterizations and properties; Part 2) Applications in catalysis; Part 3) Applications for the elaboration or modification of materials; and Part 4) Applications in biology/medicine. The role of the nanometric size and the multiple functions of dendrimers on the properties will be emphasized. Inhaltsverzeichnis Preface xvPart 1 Generalities, Syntheses, Characterizations, and Physicochemical Properties 11 Syntheses of Dendrimers and Dendrons 3Anne-Marie Caminade1.1 Introduction: What Are Dendrimers and Dendrons? 31.2 Syntheses of Poly(propyleneimine) Dendrimers (PPI) 51.3 Synthesis of Poly(amidoamine) Dendrimers (PAMAM) 51.4 Syntheses of Poly(ether) Dendrimers 71.5 Syntheses of Poly(ester) Dendrimers 101.6 Synthesis of Poly(lysine) Dendrimers 141.7 Syntheses of Silicon-Containing Dendrimers 151.8 Syntheses of Phosphorus-Containing Dendrimers 161.9 Syntheses of Carbon-Based Dendrimers 171.10 Syntheses of Dendrimers Constituted of Nitrogen Heterocycles 191.11 Syntheses by Self-Assembly 211.12 Accelerated Syntheses 261.13 Conclusion 30References 302 Methods of Characterization of Dendrimers 35Anne-Marie Caminade2.1 Introduction 352.2 Spectroscopy and Spectrometry 362.3 Scattering Techniques 47Wide-Angle X-ray Scattering (WAXS) 482.4 Microscopy 482.5 Rheology and Physical Characterizations 502.6 Separation Techniques 522.7 Conclusion 53References 543 Luminescent Dendrimers 67Anne-Marie Caminade3.1 Introduction 673.2 Dendrimers w...

Auteur

Anne-Marie Caminade is Director of Research at the Centre National de la Recherche Scientifique (CNRS) in the Laboratoire de Chimie de Coordination in Toulouse (France), where she has been head of the Molecular, Macromolecular, and Supramolecular Main Group Chemistry team (15 to 20 researchers) since 2006. Having received two Ph.Ds (1984 and 1988 in Toulouse) and two Post-docs, in industry (Institut Français du Pétrole, France, 1984) and as an Alexander von Humboldt Fellow at the University of Saarbrücken (Germany, 1988), she has been working since 1985 at the CNRS in Toulouse. Her current research interest is on the synthesis, reactivity and study of properties and applications of dendrimers and dendritic macromolecules in three main fields: Catalysis, Biology-Medicine, and Materials. She is the co-author of 278 publications and 25 patents. She is the coordinator or "scientist in charge" of several French and European projects, and received the bronze medal of the CNRS in 1989, and the Organic Chemistry Prize of the French Chemical Society in 2006.
Co-authors for the book will be members of her research team including: Dr Cédric-Olivier Turrin (biology), Dr Régis Laurent and Dr Armelle Ouali (catalysis), Dr Béatrice Delavaux-Nicot (materials).

Texte du rabat

This book will be mainly focussed on the properties and uses of dendrimers and dendrons. The aim of this book is to be the reference book about dendrimers applications. It will not describe all details, but it will give the reader a unique overview of what has currently been done with dendrimers, with numerous references and illustrations. It will be divided in four main parts: Part 1) Generalities, syntheses, characterizations and properties; Part 2) Applications in catalysis; Part 3) Applications for the elaboration or modification of materials; and Part 4) Applications in biology/medicine. The role of the nanometric size and the multiple functions of dendrimers on the properties will be emphasized.

Contenu

Preface xv Part 1 Generalities, Syntheses, Characterizations, and Physicochemical Properties 1 1 Syntheses of Dendrimers and Dendrons 3 Anne-Marie Caminade 1.1 Introduction: What Are Dendrimers and Dendrons? 3 1.2 Syntheses of Poly(propyleneimine) Dendrimers (PPI) 5 1.3 Synthesis of Poly(amidoamine) Dendrimers (PAMAM) 5 1.4 Syntheses of Poly(ether) Dendrimers 7 1.5 Syntheses of Poly(ester) Dendrimers 10 1.6 Synthesis of Poly(lysine) Dendrimers 14 1.7 Syntheses of Silicon-Containing Dendrimers 15 1.8 Syntheses of Phosphorus-Containing Dendrimers 16 1.9 Syntheses of Carbon-Based Dendrimers 17 1.10 Syntheses of Dendrimers Constituted of Nitrogen Heterocycles 19 1.11 Syntheses by Self-Assembly 21 1.12 Accelerated Syntheses 26 1.13 Conclusion 30 References 30 2 Methods of Characterization of Dendrimers 35 Anne-Marie Caminade 2.1 Introduction 35 2.2 Spectroscopy and Spectrometry 36 2.3 Scattering Techniques 47 Wide-Angle X-ray Scattering (WAXS) 48 2.4 Microscopy 48 2.5 Rheology and Physical Characterizations 50 2.6 Separation Techniques 52 2.7 Conclusion 53 References 54 3 Luminescent Dendrimers 67 Anne-Marie Caminade 3.1 Introduction 67 3.2 Dendrimers with Fluorescent Terminal Groups 68 3.3 Luminescent Group at the Core of Dendrimers and Energy/Light-Harvesting Properties 74 3.4 Fluorescent Groups inside the Structure of Dendrimers 79 3.5 Intrinsically Fluorescent Dendrimers 81 3.6 Two-Photon-Excited Fluorescence of Dendrimers 86 3.7 Conclusion 89 References 90 4 Stimuli-Responsive Dendrimers 99 Anne-Marie Caminade 4.1 Introduction 99 4.2 Photoresponsive Dendrimeric Structures 100 4.3 Thermoresponsive Dendrimeric Structures 110 4.4 Dendrimers Responsive to Solution Media Changes 114 4.5 Conclusion 117 References 118 5 Liquid Crystalline Dendrimers 125 Anne-Marie Caminade 5.1 Introduction 125 5.2 Mesogenic Groups as Terminal Functions of Dendrons 126 5.3 Mesogenic Groups as Terminal Functions of Dendrimers 131 5.4 Mesogenic Groups as Branches of Dendrimers 134 5.5 Conclusion 135 References 136 6 Dendrimers and Nanopartic…