Catalytic Carbonylation Reactions

Carbonylation reactions are of major importance in both organic and industrial chemistry. Due to the availability, price and reactivity pattern, carbon monoxide is becoming a more and more important building block for fine and bulk chemicals. The major reaction types of carbon monoxide are comprehensively discussed by leading experts from academia and industry. The authors highlight important carbonylation reactions such as hydroformylation, alkoxy-carbonylations, co/olefin-copolymerization, Pauson-Khand reactions and others. They illustrate applications in organic synthesis and give industrial examples.
This volume is designed to provide graduate students and researchers with essential information on the use of carbon monoxide in organic synthesis. Therefore, the reader will get a balanced view of this developing and complex subject.

Each volume of Topics in Organometallic Chemistry provides the broad scientific readership with a comprehensive summary and critical overview of a specific topic in organometallic chemistry. Research in this rapidly developing transdisciplinary field is having profound influence on other areas of scientific investigation, ranging from catalytic organic synthesis to biology, medicine and material science

Autorentext
Matthias Beller obtained his PhD at the University of Göttingen, Germany and completed a postdoctoral fellowship at the Massachusetts Institute of Technology in Cambridge, USA. Since 1998, he has been head of the Leibniz Institute for Organic Catalysis at University of Rostock. He is a member of the board of Dechema's Catalysis Section, the German Catalysis Competence Network ("ConNeCat") as well as the Innovationsagentur Mecklenburg-Vorpommern. He is also a member of the Association for Technical Sciences of the Union of German Academies of Sciences and Humanities.

Klappentext

In this book, leading experts from academia and industry offer a comprehensive presentation and discussion of the major reaction types of carbon monoxide. The authors highlight important carbonylation reactions such as hydroformylation, alkoxy-carbonylations, co/olefin-copolymerization, Pauson-Khand reactions and others. They illustrate applications in organic synthesis and give industrial examples. This volume is designed to provide graduate students and researchers with essential information on the use of carbon monoxide in organic synthesis.

Inhalt
Hydroformylation.- Asymmetric Hydroformylation.- Synthetic Applications of Tandem Reaction Sequences Involving Hydroformylation.- Hydroxy- and Alkoxycarbonylations of Alkenes and Alkynes.- Carbonylation of Ethene in Methanol Catalysed by Cationic Phosphine Complexes of Pd(II): from Polyketones to Monocarbonylated Products.- The PausonKhand Reaction.- Acetic Acid Synthesis by Catalytic Carbonylation of Methanol.- Carbonylations of Aldehydes.- Carbonylation of Epoxides.- Oxidative Carbonylations.