Beschreibung

Metal Catalysed Reactions in Ionic Liquids is the first non-edited book on the subject of metal catalyzed reactions in ionic liquids to cover the literature from its origins until early 2005. Following a general introduction to the field of biphasic/multiphasic catalysis, the book moves on to describe the synthesis, the functionalisation, and fundamental properties of ionic liquids relevant to catalysis. It then analyses the catalysed reactions according to their type, encompassing hydrogenation, hydroformylation, oxidation, C-C coupling reactions, metathesis, dimerisation, polymerisation and more. Trends, generalisations, advantages and disadvantages of ionic liquids for specific reaction types are also examined as well as specific processes such as supported ionic liquid phase catalysis, continuous processes using CO2 extraction and nanoparticle catalysis. Metal Catalysed Reactions in Ionic Liquids is of interest to those working in catalysis/green chemistry, in particular to advanced level undergraduate and graduate students and researchers in bi- or multiphasic catalysis using ionic liquids.

Klappentext

Metal Catalysed Reactions in Ionic Liquids

by Paul J. Dyson and Tilmann J. Geldbach

 

Metal Catalysed Reactions in Ionic Liquids is the first non-edited book on the subject of metal catalysed reactions in ionic liquids and covers the literature from its origins until early 2005.

The book begins with a general introduction to the field of biphasic/multiphasic catalysis and describes the synthesis, functionalisation and fundamental properties of ionic liquids relevant to catalysis. In the following chapters catalysed reactions are discussed according to their type, including:

hydrogenation

hydroformylation

oxidation

C-C coupling reactions

metathesis

dimerisation

polymerisation

 

Trends, generalisations, advantages and disadvantages of ionic liquids for specific reaction types are discussed. In addition, specific processes such as supported ionic liquid phase catalysis, continuous processes using CO₂ extraction and nanoparticle catalysis are covered.

This book is an invaluable resource for all those working in catalysis, green chemistry, and advanced synthetic methods, especially advanced level undergraduate and graduate students and those researching or contemplating research in biphasic or multiphasic catalysis using ionic liquids.

 

 

 

Zusammenfassung

Metal Catalysed Reactions in Ionic Liquids is the first non-edited book on the subject of metal catalyzed reactions in ionic liquids to cover the literature from its origins until early 2005.

Following a general introduction to the field of biphasic/multiphasic catalysis, the book moves on to describe the synthesis, the functionalisation, and fundamental properties of ionic liquids relevant to catalysis. It then analyses the catalysed reactions according to their type, encompassing hydrogenation, hydroformylation, oxidation, C-C coupling reactions, metathesis, dimerisation, polymerisation and more. Trends, generalisations, advantages and disadvantages of ionic liquids for specific reaction types are also examined as well as specific processes such as supported ionic liquid phase catalysis, continuous processes using CO2 extraction and nanoparticle catalysis.

Metal Catalysed Reactions in Ionic Liquids is of interest to those working in catalysis/green chemistry, in particular to advanced level undergraduate and graduate students and researchers in bi- or multiphasic catalysis using ionic liquids.

Inhalt
Introduction: A Brief History of Biphasic Catalysis.- The Importance of Biphasic Catalysis.- The Alternatives to Aqueous-Organic Biphasic Processes.- Key Developments in the Chemistry of Ionic Liquids.- General Properties of Ionic Liquids that Lend Themselves to Catalysis.-References.- Ionic Liquids Properties and Preparation: Introduction.- Composition and Physical Properties of Ionic Liquids.- Synthesis of Ionic Liquids.- Functionalised Ionic Liquids.- Toxicological and Environmental Concerns.- References.- Hydrogenation: Introduction.- Hydrogen Solubility in Ionic Liquids.- Ionic Liquids in Hydrogenation Reactions.- Ionic Liquids in Hydrogenation Reactions.- Nanoparticle Catalysts.- Supported Ionic Liquid Catalysis. Supported Ionic Liquid Catalysis.-References.- Hydroformylation: Introduction.- Gas and Substrate Solubility in Ionic Liquids .- Hydroformylation in Ionic Liquids.- Ligand Design.- Influence of the Solvent.- Special Processes.- Outlook.- References.- Oxidation Reactions: Oxidants.- Ionic Liquids for Oxidation Reactions.- Oxidation of Alkenes.- Oxidation of Alcohols and Thiols.- Other Oxidation Reactions.- Conclusion.- References.- Carbon-Carbon Coupling Reactions: Introduction.- Catalyst Stability in Ionic Liquid Mediated.- Heck Coupling Reactions.- Other Palladium Catalysed Cross-Coupling Reactions.- Allylic Alkylation.- References.- Olefin Metathesis: Introduction.- General Considerations.- Task-Specific Catalysts.- Ring -Opening Polymerisation.- Concluding Remarks.- References.- Dimerisation Polymerisation: Dimerisation and Oligomerisation.- Polymerisation.- References.- Miscellaneous Reactions.- Halogenation and De-Halogenation.- Addition to Carbon-Hetero Multiple Bonds.- Aromatic Substitution Reactions.- Cycloadditions.- Isomerisation and Rearrangements.- Addition to Carbon-Carbon Multiple Bonds.- Concluding Remarks.- References.- Index.- Abbreviations

Produktinformationen

Titel:	Metal Catalysed Reactions in Ionic Liquids
Autor:	Paul J. Dyson   Tilmann J. Geldbach
EAN:	9781402039157
ISBN:	978-1-4020-3915-7
Format:	E-Book (pdf)
Hersteller:	Springer Netherlands
Herausgeber:	Springer
Genre:	Chemie
Veröffentlichung:	24.01.2006
Digitaler Kopierschutz:	Wasserzeichen
Dateigrösse:	2.92 MB
Anzahl Seiten:	246
Jahr:	2006
Untertitel:	Englisch