Handbook of Industrial Polyethylene and Technology

This handbook provides an exhaustive description of polyethylene. The 50+ chapters are written by some of the most experienced and prominent authors in the field, providing a truly unique view of polyethylene. The book starts with a historical discussion on how low density polyethylene was discovered and how it provided unique opportunities in the early days. New catalysts are presented and show how they created an expansion in available products including linear low density polyethylene, high density polyethylene, copolymers, and polyethylene produced from metallocene catalysts. With these different catalysts systems a wide range of structures are possible with an equally wide range of physical properties. Numerous types of additives are presented that include additives for the protection of the resin from the environment and processing, fillers, processing aids, anti-fogging agents, pigments, and flame retardants. Common processing methods including extrusion, blown film, cast film, injection molding, and thermoforming are presented along with some of the more specialized processing techniques such as rotational molding, fiber processing, pipe extrusion, reactive extrusion, wire and cable, and foaming processes. The business of polyethylene including markets, world capacity, and future prospects are detailed. This handbook provides the most current and complete technology assessments and business practices for polyethylene resins.

Autorentext

Mark A. Spalding is a Fellow in the Materials & Parts Processing Group at The Dow Chemical Company, Midland, MI. He joined Dow in 1985 after completing a BS from The University of Toledo and a MS and PhD from Purdue University, all in Chemical Engineering. He has performed fundamental research in single-screw extrusion, developed methods to measure resin physical properties that are important to polymer processing, developed numerous techniques to troubleshoot and increase the rates of extrusion lines, and has developed new mathematical models for extrusion simulation. He co-authored the book "Analyzing and Troubleshooting Single-Screw Extruders" with Gregory A. Campbell. Dr. Spalding is a Fellow and Honored Service Member of the Society of Plastics Engineers (SPE).

Ananda M. Chatterjee started his career at Celanese Plastics (1978) and worked for Shell Development, Union Carbide, Dow Chemical, Kaneka Texas, and Ingenia Polymers. He had extensive and in-depth experience in polymer research and development, product commercialization, polymer film processing and products technology, polymer additives technology, additive blends technology and processing, customer technical service, intellectual property (patent) invention and licensing and technology transfer of UNIPOL polypropylene technology worldwide. He was a Fellow and Honored Service Member of the Society of Plastics Engineers (SPE). Dr. Chatterjee held a PhD from the University of Massachusetts Amherst and held over 25 U.S. patents. Dr. Chatterjee passed away in 2016 during the development of this book.

Klappentext
This two-part handbook provides detailed and comprehensive coverage of the world's leading plastic material and will become the premier polyethylene text for the next decade.

This handbook provides an exhaustive description of polyethylene. The 51 chapters are written by some of the most experienced and prominent authors in the field, providing a truly unique view of polyethylene. The book starts with a historical discussion on how low density polyethylene was discovered and how it provided unique opportunities in the early days. New catalysts are presented and show how they created an expansion in available products including linear low density polyethylene, high density polyethylene, copolymers, and polyethylene produced from metallocene catalysts. With these different catalysts systems a wide range of structures are possible with an equally wide range of physical properties. Numerous types of additives are presented that include additives for the protection of the resin from the environment and processing, fillers, processing aids, anti-fogging agents, pigments, and flame retardants. Common processing methods including extrusion, blown film, cast film, injection molding, and thermoforming are presented along with some of the more specialized processing techniques such as rotational molding, fiber processing, pipe extrusion, reactive extrusion, wire and cable, and foaming processes. The business of polyethylene including markets, world capacity, and future prospects are detailed. This handbook provides the most current and complete technology assessments and business practices for polyethylene resins. "No other book on the market today brings all these elements together into a single resource in such a useful way. Resin producers, additive suppliers, equipment manufacturers, fabricators, and end-users alike will find this book invaluable for understanding this polymer technology". Barry Morris, Technical Fellow, DuPont Audience
This handbook will be used extensively by engineers working in the polyethylene industry such as resin purchasers and suppliers, compounding houses, additive suppliers and equipment manufacturers for PE converters. On the academic side, chemical engineers, plastics technologists, industrial manufacturing engineers/researchers will find the handbook extremely useful.

Inhalt
Foreword by Barry Morris xi

Preface xiii

List of Contributors xv

Part 1: Principles and Properties of Polyethylene

1 An Industrial Chronology of Polyethylene 3
Christopher Dobbin

2 Catalysts for the Manufacture of Polyethylene 25
Yury V. Kissin

3 Ethylene Polymerization Processes and Manufacture of Polyethylene 61
Ian D. Burdett and Ronald S. Eisinger

4 Types and Basics of Polyethylene 105
Rajen M. Patel

5 Molecular Structural Characterization of Polyethylene 139
A. Willem deGroot, David Gillespie, Rongjuan Cong, Zhe Zhou and Rajesh Paradkar

6 Thermal Analysis of Polyethylene 217
Kevin Menard and Noah Menard

7 Rheology of Polyethylene 239
Gregory W. Kamykowski

8 Processing-Structure-Property Relationships in Polyethylene 283
Rajen M. Patel

9 Mechanical Properties of Polyethylene: Deformation and Fracture Behavior 309
Alexander Chudnovsky, and Kalyan Sehanobish

Part 2: Processing and Fabrication of Polyethylene

10 Single-Screw Extrusion of Polyethylene Resins 339
Mark A. Spalding

11 Twin-Screw Extrusion of Polyethylene 357
Yoshitaka Kumura, Amit K. Chaudhary and Mark A. Spalding

12 Blown Film Processing 381
Thomas I. Butler

13 Cast Film Extrusion of Polyethylene 411
Hyunwoo Kim, Mark A. Spalding, Kurt A. Koppi, Wes Hobson and Joseph Dooley

14 Extrusion Coating and Laminating 429
Thomas Bezigian

15 Injection Molding 443
Jon Ratzlaff and Thomas Giovannetti

16 Blow Molding of Polyethylene 475
Mohammad Usman and Abdul Sami Siddiqui

17 Rotational Molding 535
Jon Ratzlaff and Glenn E. Larkin, Jr.

18 Thermoforming Polyethylene 573
Roger C. Kipp

19 Polyethylene Pipe Extrusion 591
Pam Maeger, V. Rohatgi, D. Hukill, N. Koganti and B. Martinez

20 Polyethylene Foam Extrusion 603
N. S. Ramesh

21 Expanded Polyethylene Bead Foam Technology 637
Steven R. Sopher

22 Polyethylene Fiber Extrusion 669
Johannes Fink

23 Polyethylene Compounding Technologies 695
Charles D. Park II and Steven Blazey

24 Polyethylene Modification by Reactive Extrusion 715
Adriana I. Moncada, Wenyi Huang and Nicholas Horstman

Part 3: Additives for Polyethylene

25 Degradation and Stabilization of Polyethylene 753
Joseph J. Fay and Roswell E. King, III

26 Light Stabilization of Polyethylene 771
Feng Zuo and Tad Finnegan

27 Acid Scavengers for Polyethylene 793
*Robert L. Sherman Jr. and Kimberly…