Giant Micelles

Enhanced with tables and figures, this text explores the giant micelles that occur in many types of surfactant solutions. It focuses on the theoretical aspects of their formation from different viewpoints, including molecular thermodynamic theory and computer simulations. It also examines their rheological behavior and addresses experimental findings from the application of transmission electron microscopy at cryogenic temperature, scattering methods, phase diagrams, linear and nonlinear rheology, and chemical relaxation. The text includes discussion of various applications, including energy production, drag reduction, cleansers, cosmetics, and personal care products.

Autorentext

Raoul Zana, Eric W. Kaler

Zusammenfassung
The co-evolution of a strong theoretical framework alongside application of a range of sophisticated experimental tools engendered rapid advancement in the study ofgiant micelles. Beginning with Anacker and Debye's 1951 experimental study of elongated micelles by light scattering and their subsequent theoretical inference that the thermodynamic

Inhalt

Molecular Thermodynamics of Giant Micelles, Molecular Packing in Cylindrical Micelles, Computer Simulations of Wormlike Micelles, Theoretical Rheology of Giant Micelles, Seeing Giant Micelles by Cryogenic-Temperature Transmission Electron Microscopy (Cryo-TEM), Scattering from Wormlike Micelles, Phase Behavior of Systems with Wormlike Micelles, Linear Rheology of Aqueous Solutions of Wormlike Micelles, Nonlinear Rheology of Giant Micelles, Relaxation in Wormlike Micelle Solutions, Giant Micelles at and Near Surfaces, Stimuli-Responsive Giant Micellar Systems, Hydrogen Bonded Supramolecular Polymers versus Wormlike Micelles: Similarities and Specificities, Nonionic Block Copolymer Wormlike Micelles, Oilfield Applications of Giant Micelles, Drag Reduction by Surfactant Giant Micelles, Giant Micelles and Shampoos, Daily Applications of Systems with Wormlike Micelles,