Diese übersichtlich in zwei Teile gegliederte Monographie behandelt die Grundlagen der Elektropolymerisation ebenso ausführlich w...
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Diese übersichtlich in zwei Teile gegliederte Monographie behandelt die Grundlagen der Elektropolymerisation ebenso ausführlich wie fortgeschrittene Spezialanwendungen. Autorentext Serge Cosnier is Research Director at CNRS and head of the Analytical and Electrochemical Biosystems Lab at Joseph Fourier University of Grenoble, France, where he began his research career in 1983. He received his Ph.D. in chemistry from Paul Sabatier University of Toulouse in 1982 and then was an Alexander von Humboldt postdoctoral fellow at Munich University. Since 2001, he is the President of the French Group of Bioelectrochemistry and was elected in 2007 President of the Rhone-Alpes section of the Chemical Society of France. Dr. Cosnier has authored over 205 publications and was awarded two national prizes of the French Club of Chemical Microsensors. In 2009, he received the Katsumi Niki Prize for Bioelectrochemistry of the International Society of Electrochemistry.
Arkady A. Karyakin is professor of chemistry and head of the Electrochemical Methods Laboratory, Chemistry faculty of M.V. Lomonosov Moscow State University (MSU). He graduated from MSU in 1981, receiving his Ph.D. and D.Sc. in 1986 and 1996, respectively. Starting from 2010, A.A. Karyakin is Associate Editor of "Electroanalysis" (Wiley-VCH). He also serves as editorial board member on numerous journals. Professor Karyakin is author of more than 100 papers and contributor to the Encyclopedia of Sensors. He has received several awards in chemistry including the Russian Presidential Award. Zusammenfassung Providing extensive coverage, including conducting, insulating and electroactive films, this handbook and ready reference deals with introductory topics and fundamentals as well as advanced insights. Clearly structured, in the first part of the book readers learn the fundamentals of electropolymerizatoin for all important types of polymers, mechanisms of film formation and functionalization, while the second part covers a wide range of applications in biochemistry, analytics, photovoltaics, energy and the environment as well as actuators. Inhalt Preface ELECTROPOLYMERIZED FILMS OF PI-CONJUGATED POLYMERS. A TOOL FOR SURFACE FUNCTIONALIZATIONS: A BRIEF HISTORICAL EVOLUTION AND RECENT TRENDS Introduction Electropolymerization: Epistemological Analysis within the ICP Saga Electropolymerization: From Pristine Heterocyclic to Sophisticated Functional and Conjugated Architectures Conclusion MECHANISMS OF ELECTROPOLYMERIZATION AND REDOX ACTIVITY: FUNDAMENTAL ASPECTS Electropolymerization: General Aspects Redox Activity of Polymer Films Effect of Polymerization Parameters on Properties of Deposited Polymer Films Conclusions ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY (EIS) FOR POLYMER CHARACTERIZATION Introduction Experimental Arrangements Impedance Spectra of Polymer Films Analysis of the Impedance Spectra Models of Polymeric Layers Summary RECENT TRENDS IN POLYPYRROLE ELECTROCHEMISTRY, NANOSTRUCTURATION, AND APPLICATIONS Introduction Advances in Synthetic Procedures - New Polymers Nanostructuration of Polypyrrole Applications Conclusion ELECTROPOLYMERIZED AZINES: A NEW GROUP OF ELECTROACTIVE POLYMERS Introduction Electropolymerized Azines as a New Group of Electroactive Polymers Polyazines in Electroanalysis Electropolymerized Azines as Promoters for Bioelectrocatalysis Conclusion ELECTROPOLYMERIZATION OF PHTHALOCYANINES Introduction Immobilization of Transition-Metal Phthalocyanines on Conducting and Nonconducting Substrates Electropolymerization of Phthalocyanines Conclusion IMPRINTED POLYMERS Introduction Molecular Imprinting in Conjugated Polymers Solgel Imprinted Films Prepared by Electropolymerization Integration of MIPs with the Surface of Transducers Nanostructured Materials Other MIP-Based Sensors Conclusion GAS SENSING WITH CONDUCTING POLYMERS Introduction Electronic Properties of Conducting Polymers Preparation of Polymer Gas-Sensing Layers Mechanism of Gas/Polymer Interactions Types of Conducting Polymer-Based Gas Sensors Conclusion CHEMICAL SENSORS BASED ON CONDUCTING POLYMERS Introduction Electrochemical Signal Transduction Optical Signal Transduction Conclusions BIOSENSORS BASED ON ELECTROPOLYMERIZED FILMS Introduction Chronological Evlution of the Concept of Biosensors Based on Electropolymerized Films: Principal Stages Formation of Polymer Films by Direct Electropolymerization of the Biomolecule Adsorption on Electrogenerated Polymers Mechanical Entrapment within Electropolymerized Films Covalent Binding at the Surface of Electropolymerized Films Noncovalent Binding by Affinity Interactions with the Electropolymerized Films Outlook INHERENTLY CONDUCTING POLYMERS VIA ELECTROPOLYMERIZATION FOR ENERGY CONVERSION AND STORAGE Introduction Energy Conversion Energy Storage Electropolymerization to Form Electrodes for Energy Storage Applications Nanostructured Conducting Polymers Conducting Polymer Composites Conclusions ELECTROCHEMOMECHANICAL DEVICES: ARTIFICIAL MUSCLES Introduction Conducting Polymers as Reactive Materials: Electrochemical Reactions Electrochemical Properties: Multifunctionality and Biomimetism Macroscopic Dimensional Changes and Mechanical Properties Anisotropy Obtained from Isotropic Changes: Macroscopic Devices Electrochemical Characterization Sensing Capabilities of Artificial Muscles Tactile Sensitivity Intelligent Devices Muscles Working in Air Advantages, Limitations, and Challenges Artificial Muscles as Products