Chemistry in Anhydrous, Prototropic Solvents

Chemistry in Nonaqueous Ionizing Solvents: Volume II - Part 1 investigates the chemical and physico-chemical properties of substances dissolved or suspended in non-aqueous ionizing solvents (also known as water-like solvents). This volume is concerned with chemistry in anhydrous hydrogen cyanide and with inorganic chemistry in liquid hydrogen fluoride.
This book is comprised of 35 chapters that cover topics ranging from commercial preparation of hydrogen fluoride to laboratory preparation of pure hydrogen fluoride as well as deuterium and tritium fluorides. Experimental techniques and the apparatus used in investigations of liquid hydrogen fluoride are also described. Subsequent chapters explore health risks and first aid with respect to handling hydrogen fluoride; physical properties of the pure solvent; inorganic solvates; solubilities and reactions of inorganic compounds; and acids and bases and their reactions with each other. The last two chapters are devoted to fluorides of the lanthanides and actinides in hydrogen fluoride.
This monograph will be of interest to chemists.

Inhalt

Part 1 Anorganische Chemie in flüssigem Cyanwasserstoff

1. Das Lösungsmittel flüssiger Cyanwasserstoff
   1.1. Physikalische Daten des reinen Solvens
   1.2. Struktur des Solvens HCN
2. Das Verhalten anorganischer Verbindungen im Lösungsmittel Cyanwasserstoff
   2.1. Additionsverbindungen mit Cyanwasserstoff (Solvate)
   2.2. Die Löslichkeit von anorganischen Substanzen und Salzen organischer Ionen in flüssigem Cyanwasserstoff
   2.3. Lösungszustand
   2.4. Das Solvosystem des flüssigen Cyanwasserstoffs
   2.5. Das Verhalten von "Säure-Basen" - Indikatoren in flüssigem wasserfreiem Cyanwasserstoff
   2.6. Neutralisationenanaloge Reaktionen in flüssigem Cyanwasserstoff
   2.7. Solvolyse-Reaktionen in wasserfreiem Cyanwasserstoff
   2.8. Die Erscheinung der Amphoteric in flüssigem Cyanwasserstoff
   2.9. Weitere Reaktionen in flüssigem Cyanwasserstoff
3. Das Verhalten organischer Verbindungen im Lösungsmittel Cyanwasserstoff
   3.1. Additionsverbindungen mit Cyanwasserstoff (Solvate)
   3.2. Die Löslichkeit von organischen Verbindungen in wasserfreiem Cyanwasserstoff
   3.3. Lösungszustand
   3.4. Solvolysereaktionen organischer Verbindungen in wasserfreiem Cyanwasserstoff
   3.5. Bemerkung über weitere Reaktionen organischer Verbindungen in und mit Cyanwasserstoff
4. Literaturverzeichnis
   Sachwortverzeichnis
   Part 2 Inorganic Chemistry in Liquid Hydrogen Fluoride
5. Commercial Preparation of Hydrogen Fluoride
6. Laboratory Preparation of Pure Hydrogen Fluoride
7. Laboratory Preparation of Deuterium and Tritium Fluorides
8. Preparation of 18 F-Labeled Hydrogen Fluoride
9. Experimental Techniques
   5.1. Constructional Materials
   5.2. Apparatus
10. Health Risks and First Aid
11. Physical Properties of the Pure Solvent
12. Structure of the Solvent
    8.1. Solid Hydrogen Fluoride
    8.2. Gaseous Hydrogen Fluoride
    8.3. Liquid Hydrogen Fluoride
13. Inorganic Solvates
14. Solubilities and Reactions of Inorganic Compounds
    10.1. Introductory Remarks
    10.2. Elements
    10.3. Halides
    10.4. Oxides, Hydroxides, and Salts of Oxyacids
    10.5. Azides, Cyanides and Sulphides
    10.6. Miscellaneous
15. Acids and Bases
    11.1. Formal Definitions
    11.2. Quantitative Measurements
    11.3. Basic Solutes
    11.4. Acidic Solutes
    11.5. Neutral Solutes
16. Acid-Base Reactions
    12.1. Conductimetric and Tensimetric Titrations
    12.2. Preparative Reactions
    12.3. Solvolysis of Fluoro Anions
    12.4. Amphoteric Behavior
17. Redox Reactions
    13.1. Electrode Potentials
    13.2. Polarography
    13.3. Electrolytic Reactions
    13.4. Chemical Agents
18. Complexions
    14.1. Fluoro Anions
    14.2. Complex Cations
19. H2O-HF System
    15.1. Hydrofluoric Acid
    15.2. Wet Hydrogen Fluoride
    15.3. Hammett Acidity Function
    15.4. Phase Diagram
    15.5. Vapor Pressures and Boiling Points
    15.6. Density Measurements
    15.7. Conductivity Measurements
    15.8. Infrared Spectroscopy
    15.9. Nuclear Magnetic Resonance Spectroscopy
    15.10. Solvent Extraction
20. SO2-HF System
21. Alkali Metal Fluorides in HF
    17.1. Lithium Fluoride
    17.2. Sodium Fluoride
    17.3. Potassium Fluoride
    17.4. Rubidium Fluoride
    17.5. Cesium Fluoride
22. Ammonium and Substituted Ammonium Fluorides in HF
    18.1. Ammonium Fluoride
    18.2. Substituted Ammonium Fluorides
23. Group II Metal Fluorides in HF
    19.1. Beryllium Fluoride
    19.2. Magnesium Fluoride
    19.3. Calcium Fluoride
    19.4. Strontium Fluoride
    19.5. Barium Fluoride
24. Group III Fluorides in HF
    20.1. Boron Trifluoride
    20.2. Aluminum Trifluoride
    20.3. Gallium Fluorides
    20.4. Indium Trifluoride
    20.5. Thallium Fluorides
25. Group IV Fluorides in HF
    21.1. Carbon Fluorides
    21.2. Silicon Tetrafluoride
    21.3. Germanium Tetrafluoride
    21.4. Tin Fluorides
    21.5. Lead Fluorides
26. Group V Fluorides in HF
    22.1. Nitrogen Fluorides and Oxyfluorides
    22.2. Phosphorus Fluorides
    22.3. Arsenic Fluorides
    22.4. Antimony Fluorides
    22.5. Bismuth(IH) Fluoride
27. Group VI Fluorides in HF
    23.1. Oxygen Difluoride
    23.2. Sulphur Fluorides and Oxyfluorides
    23.3. Selenium(IV) Fluoride
    23.4. Tellurium (IV) Fluoride
28. Halogen Fluorides in HF
    24.1. Chlorine Fluoride
    24.2. Bromine Fluorides
    24.3. Iodine Fluorides and Oxyfluorides
29. Noble Gas Fluorides in HF
    25.1. Krypton(II) Fluoride
    25.2. Xenon Fluorides
30. Titanium, Zirconium and Hafnium Fluorides in HF
    26.1. Titanium(IV)
    26.2. Zirconium(IV)
    26.3. Hafnium(IV)
31. Vanadium, Niobium and Tantalum Fluorides in HF
    27.1. Vanadium(IV)
    27.2. Vanadium(V)
    27.3. Niobium(V)
    27.4. Tantalum(V)
32. Chromium, Molybdenum and Tungsten Fluorides in HF
    28.1. Chromium(III)
    28.2. Chromium(VI)
    28.3. Molybdenum(V)
    28.4. Molybdenum(VI)
    28.5. Tungsten(VI)
33. Manganese and Rhenium Fluorides in HF
    29.1. Manganese(III)
    29.2. Manganese(VII)
    29.3. Rhenium(VI)
    29.4. Rhenium(VII)
34. Iron, Cobalt and Nickel Fluorides in HF
    30.1. Iron
    30.2. Cobalt
    30.3. Nickel(II)
    30.4. Nickel(III)
    30.5. Nickel(IV)
35. Palladium, Osmium, and Platinum Fluorides in HF
    31.1. Palladium(IV)
    31.2. Osmium(VI)
    31.3. Platinum(II)
    31.4. Platinum(IV)
36. Copper and Silver Fluorides in HF
    32.1. Copper(II)
    32.2. Silver(I)
    32.3. Silver (II)
37. Zinc, Cadmium and Mercury Fluorides in HF
    33.1. Zinc(II), Cadmium(II) and Mercury(I)
    33.2. Mercury(II)
38. Fluorides of the Lanthanides in HF
39. Fluorides of the Actinides in HF
    35.1. Thorium(IV)
    35.2. Uranium(IV)
    35.3. Uranium(V)
    35.4. Uranium(VI)
    35.5. Neptunium(IV) and Neptunium(V)
    35.6. Plutonium(VI)
    References
    Index